Assembly of Supramolecular Networks with the Inclusion of T4(2)6(2) Water Tapes and R6 Water Clusters

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• 作者：Wan-Dan Weng ; Yue-Qing Zheng ; Hong-Lin Zhu ; Jian-Qing Xu
• 关键词：Water tape ; Water cluster ; Meso ; 2 ; 3 ; dibromosuccinic acid ; Crystal structures
• 刊名：Journal of Cluster Science
• 出版年：2015
• 出版时间：September 2015
• 年：2015
• 卷：26
• 期：5
• 页码：1833-1843
• 全文大小：1,133 KB
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• 作者单位：Wan-Dan Weng (1)
  Yue-Qing Zheng (1)
  Hong-Lin Zhu (1)
  Jian-Qing Xu (1)
  
  1. Research Center for Solid State Chemistry & Application, Ningbo University, Ningbo, 315211, People’s Republic of China
  
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Catalysis
  Inorganic Chemistry
  Physical Chemistry
  
• 出版者：Springer Netherlands
• ISSN：1572-8862

文摘

Two new supramolecular compounds were synthesized and characterized with the formula of [Cu(bipy)₂(OAc)]·(DBrS)_1/2·5H₂O 1, [Co(phen)₂(CO₃)]·(DBrS)_1/2·5H₂O 2 (H₂DBS = meso-2,3-dibromosuccinic acid; bipy = 2,2-bipyridine; phen = 1,10-phenanthroline). The crystal structures of complexes were determined by X-ray single-crystal diffraction. Complex 1 represents R6 water clusters and complex 2 stabilizes in a 1D water tape notated T4(2)6(2). For 2, the 2D layer is defined as a 2D (3,4,6)-connected network with the Schl?fli symbol of (4·5·6)₄(42·5·6·72)(42·5)₂(44·52·62·74·93). Results about i.r. spectra and elemental analyses are presented. Keywords Water tape Water cluster Meso-2,3-dibromosuccinic acid Crystal structures