Unusual 1D Tape of Pentameric and Tetrameric Water Clusters Trapped in a 2D Cobalt(II) Coordination Polymer: Synthesis, Characterization, and Catalytic Properties

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• 作者：Liang Qin ; Kuan Lu ; Xiang Li ; Jingjing Yan…
• 关键词：Cobalt coordination polymer ; Water cluster ; Hydrogen bonds ; Crystal structure ; Catalytic properties
• 刊名：Journal of Inorganic and Organometallic Polymers and Materials
• 出版年：2016
• 出版时间：March 2016
• 年：2016
• 卷：26
• 期：2
• 页码：460-466
• 全文大小：2,588 KB
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• 作者单位：Liang Qin (1)
  Kuan Lu (1)
  Xiang Li (1)
  Jingjing Yan (1)
  Weijie Lin (1)
  Wanqiu Ding (1)
  Husheng Lu (1)
  Dongting Lin (1)
  Deyun Ma (1)
  Fenglan Liang (2)
  
  1. School of Chemistry and Chemical Engineering, Zhaoqing University, Zhaoqing, 526061, People’s Republic of China
  2. College of Life Science, Zhaoqing University, Zhaoqing, 526061, People’s Republic of China
  
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Inorganic Chemistry
  Organic Chemistry
  Polymer Sciences
  
• 出版者：Springer New York
• ISSN：1574-1451

文摘

1D tape of pentameric and tetrameric water clusters have been observed in a complex of [Co(oba)(H₂O)₃]·(H₂O)₂·(dmbpy)]_n (1), (H₂oba = 4,4′-oxybis(benzoic acid), dmbpy = 2,2′-dimethyl-4,4′-bipyridine), which has been synthesized and characterized by elemental analysis, IR spectroscopy, thermogravimetric analysis (TGA), powder X-ray diffraction and single-crystal X-ray diffraction. In 1, a cyclic pentamer formed by four water molecules and one carboxylate oxygen, as well as a chain-like tetrameric water-(carboxyl oxygen) cluster are observed. The uncoordinated carboxylate oxygen atoms of oba anions, water molecules and free dmbpy ligands interact via hydrogen bonds forms a tape in which the dmbpy ligands point alternately up and down, and extend 2D 1 into a 3D supramolecular structure. Moreover, 1 has a remarkable activity for degradation of methyl orange in a photo-assisted Fenton-like process.