Organic reagents for the identification of Bi(V) and O 2 2-/sup> in Ba–Bi–O and K–Ba–Bi–O oxides using field test methods

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• 作者：N. V. Barkovskii
• 关键词：organic reagents ; aromatic amines ; dyes ; Ba–Bi–O and K–Ba–Bi–O oxide systems ; valence state ; Bi(V) ; peroxide ions O 2 2- detection limit
• 刊名：Journal of Analytical Chemistry
• 出版年：2015
• 出版时间：November 2015
• 年：2015
• 卷：70
• 期：11
• 页码：1346-1353
• 全文大小：293 KB
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• 作者单位：N. V. Barkovskii (1)
  
  1. Institute of Solid State Physics, Russian Academy of Sciences, ul. Akademika Osip’yana 2, Chernogolovka, Moscow oblast, 142432, Russia
  
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Analytical Chemistry
  Russian Library of Science
  
• 出版者：MAIK Nauka/Interperiodica distributed exclusively by Springer Science+Business Media LLC.
• ISSN：1608-3199

文摘

We investigated the interaction of aromatic amines, such as diphenylamine (DPA), Arnold’s base (AB), benzidine (B), and o-tolidine (OT), and dyes, namely, Methyl Red (MR), Chromazurol S (CA), Arsenazo III (A), Indigo Carmine (IC), and Thoron (T), with Bi₂O₃, Bi₂O_4.09, NaBiO₃, BaBiO₃, BaBi₃O_5.55, BaBi₅O_8.5, and K _n Ba _m Bi _{m + n} O _y (n = 1-; m = 1, 3-) oxides, having superconducting properties (T _s = 28-2 K), and BaO₂ and H₂O₂ peroxides. Among the studied amines, only Arnold’s base is not oxidized by peroxides and can serve as a reagent for the identification of peroxide dioxygen O ₂ 2-/sup> and Bi(V). It was found that Bi(V), unlike O ₂ 2-/sup> , oxidizes acidic solutions of Methyl Red, Chromazurol S, Arsenazo III, Thoron, and Indigo Carmine, decolorizing them; that is, these dyes may be used in the test methods for identifying Bi(V) and O ₂ 2-/sup> . It was found that, in reactions with amines and dyes, Bi(V) is a stronger oxidant than O ₂ 2-/sup> . The detection limits for Bi(V) with DPA, Arnold’s base, benzidine, o-tolidine, Methyl Red, Indigo Carmine, and Thoron are determined. Keywords organic reagents aromatic amines dyes Ba–Bi–O and K–Ba–Bi–O oxide systems valence state Bi(V) peroxide ions O ₂ 2-/sup> detection limit