Cyclic Degradation of Co49Ni21Ga30 High-Temperature Shape Memory Alloy: On the Roles of Dislocation Activity and Chemical Order

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• 作者：P. Krooß ; P. M. Kadletz ; C. Somsen ; M. J. Gutmann…
• 关键词：Shape memory alloy (SMA) ; Martensitic phase transformation ; Functional degradation ; Martensite stabilization ; Superelasticity
• 刊名：Shape Memory and Superelasticity
• 出版年：2016
• 出版时间：March 2016
• 年：2016
• 卷：2
• 期：1
• 页码：37-49
• 全文大小：1,775 KB
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• 作者单位：P. Krooß (1)
  P. M. Kadletz (2)
  C. Somsen (3)
  M. J. Gutmann (4)
  Y. I. Chumlyakov (5)
  W. W.  Schmahl (2)
  H. J. Maier (6) (7)
  T. Niendorf (1)
  
  1. Institut für Werkstofftechnik, Universität Kassel, 34125, Kassel, Germany
  2. Applied Crystallography, Department of Earth and Environmental Sciences, Ludwig-Maximilians-Universität, 80333, Munich, Germany
  3. Institut für Werkstoffe, Ruhr-Universität Bochum, 44801, Bochum, Germany
  4. Rutherford Appleton Laboratory, ISIS Facility, Chilton Didcot, Oxfordshire, OX11 0QX, UK
  5. Siberian Physical Technical Institute, Tomsk State University, Novosobornay Square 1, Tomsk, Russia, 634050
  6. Institut für Werkstoffkunde (Materials Science), Leibniz Universität Hannover, 30823, Garbsen, Germany
  7. Zentrum für Festkörperchemie und Neue Materialien, Leibniz Universität Hannover, 30167, Hannover, Germany
  
• 刊物类别：Characterization and Evaluation of Materials;
• 刊物主题：Characterization and Evaluation of Materials;
• 出版者：Springer International Publishing
• ISSN：2199-3858

文摘

Conventional shape memory alloys (SMAs), such as binary Ni–Ti, are typically limited to service temperatures below 100 °C. Recent studies on Co–Ni–Ga high-temperature SMAs revealed the potential that these alloys can be used up to temperatures of about 400 °C. Analysis of the cyclic functional properties showed that degradation in these alloys is mainly triggered by intensive dislocation motion. However, data on the cyclic stress–strain response and the mechanisms leading to functional degradation of Co–Ni–Ga above 300 °C were missing in open literature. Current results reveal that above 300 °C diffusion-controlled mechanisms, e.g., precipitation of secondary phases and changes in the chemical degree of order, seem to dictate cyclic instability. Detailed neutron and transmission electron microscopy analyses following superelastic cycling in a temperature range of 200–400 °C were employed to characterize the changes in degradation behavior above 300 °C.