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作者单位:Tinghua Wang (1) Xiaokai Zhang (2) Xue Li (1) Xinkang Gao (1) Lianlian Song (1)
1. Shandong Provincial Key Laboratory of Fluorine Chemistry and Chemical Materials, School of Chemistry and Chemical Engineering, University of Jinan, No. 336 West Road of Nan Xinzhuang, Jinan, 250022, People’s Republic of China 2. College of Physics and Electronics, Shandong Normal University, 88 Wenhuadong Road, Jinan, 250014, People’s Republic of China
刊物类别:Chemistry and Materials Science
刊物主题:Chemistry Polymer Sciences Characterization and Evaluation Materials Soft Matter and Complex Fluids Physical Chemistry
出版者:Springer Berlin / Heidelberg
ISSN:1436-2449
文摘
In this paper, the crystallization of poly(2-vinyl pyridine)-block-poly(ethylene oxide) (P2VP-b-PEO) block copolymer micelles with an amorphous P2VP core and crystallizable PEO corona upon cooling in n-amyl acetate/n-butanol (NAA/BOL) mixed solvent was investigated. The micellar solutions of the block copolymers were quenched from 65 to −33 °C first and then to the crystallization temperature −3 °C. Transmission electron microscopy was used to observe the morphological changes of the block copolymers. The influence of the solubility or chain mobility of the P2VP core on the formation of square crystals was investigated. Square crystals of uniform size and shape in large quantities could be obtained. The crystals are composed of PEO single-crystal layer sandwiched between two P2VP layers tethered on the top and bottom basal surfaces. The crystallization mechanism that spherical micelles transform into squared crystals is discussed.