Model compounds of iron gall inks ᾿a Mössbauer study
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- 作者：A. Lerf ; F. E. Wagner
- 关键词：Mössbauer spectroscopy ; Ferrogallic ink ; Ancient documents ; Model compounds
- 刊名：Hyperfine Interactions
- 出版年：2016
- 出版时间：December 2016
- 年：2016
- 卷：237
- 期：1
- 全文大小：1,582 KB
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F. E. Wagner (2)
1. Walther Meiβner Institute, Bavarian Academy of Sciences, 85747, Garching, Germany
2. Physics Department E15, Technical University of Munich, 85747, Garching, Germany - 刊物类别：Physics and Astronomy
- 刊物主题：Physics
Nuclear Physics, Heavy Ions and Hadrons
Atoms, Molecules, Clusters and Plasmas
Condensed Matter
Surfaces and Interfaces and Thin Films - 出版者：Springer Netherlands
- ISSN：1572-9540
文摘
Ferrogallic inks were used for at least two millennia before they became obsolete in the 20th century. The chemistry of such inks is, however, still largely unclear. Today it is of particular interest for the conservation of old manuscripts. 57Fe Mössbauer spectra of the ink on historical documents showed the presence of Fe(II) oxalate and of Fe(III) sites presumably representing iron oxihydroxides. To obtain more information on the behaviour of ink on paper we have performed Mössbauer studies at 300 and 4.2 K on iron gall inks prepared from FeSO4⋅7H2O and tannin. These inks were either written on paper or isolated as a precipitate by centrifugation. In the dried precipitate there is still a strong contribution of the FeSO4⋅7H2O which is absent in the same ink written on paper, for which a broad ferrous component with a quadrupole splitting (QS) of about 2.5 mm/s was found. The dominant Fe(III) site present in all inks on paper with QS ≈ 0.82 mm/s is not Fe(III) gallate and different from the precipitates. We propose that nanoparticulate oxidic clusters or molecular composites covered by a shell of polymerized oxidation products of the phenols are formed on the paper.