Energy cycle based on a high specific energy aqueous flow battery and its potential use for fully electric vehicles and for direct solar-to-chemical energy conversion
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- 作者：Yuriy V. Tolmachev ; Andrii Piatkivskyi…
- 刊名：Journal of Solid State Electrochemistry
- 出版年：2015
- 出版时间：September 2015
- 年：2015
- 卷：19
- 期：9
- 页码：2711-2722
- 全文大小：1,333 KB
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Andrii Piatkivskyi (2)
Victor V. Ryzhov (2)
Dmitry V. Konev (3) (4)
Mikhail A. Vorotyntsev (3) (4) (5) (6)
1. Ftorion, Inc., Boston, MA, 02120, USA
2. Northern Illinois University, DeKalb, IL, 60115, USA
3. Institute for Problems of Chemical Physics, Chernogolovka, Russia
4. Mendeleev University of Chemical Technology of Russia, Moscow, Russia
5. Lomonosov Moscow State University, Moscow, Russia
6. ICMUB UMR 6302 CNRS, Universite de Bourgogne, Dijon, France - 刊物类别：Chemistry and Materials Science
- 刊物主题：Chemistry
Physical Chemistry
Analytical Chemistry
Industrial Chemistry and Chemical Engineering
Characterization and Evaluation Materials
Condensed Matter
Electronic and Computer Engineering - 出版者：Springer Berlin / Heidelberg
- ISSN：1433-0768
文摘
A flow battery employing H2 as the fuel and one or more of highly soluble halate salts (such as 50 % w/w LiBrO3 aq.) as the oxidant presents a viable opportunity as a power source for fully electric vehicles which meets the specific energy, specific power, energy efficiency, cost, safety, and refill time requirements. We further disclose a process of regeneration of the fuel and the oxidant from the discharged halide salt and water using electric (or solar) energy as the only input and generating no chemical waste. The cycle of discharge and regeneration takes advantage of pH-driven comproportionation and disproportionation reactions, respectively, and of pH manipulation using an orthogonal ion migration across laminar flow (OIMALF? reactor. This article is dedicated to Prof. M.A. Vorotyntsev on the occasion of his 70th jubilee.