Impact of anionic polyacrylamide on stability and surface properties of the Al2O3–polymer solution system at different temperatures
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- 作者：Małgorzata Wiśniewska ; Stanisław Chibowski ; Teresa Urban…
- 刊名：Colloid & Polymer Science
- 出版年：2016
- 出版时间：September 2016
- 年：2016
- 卷：294
- 期：9
- 页码：1511-1517
- 全文大小：650 KB
- 刊物类别：Chemistry and Materials Science
- 刊物主题：Chemistry
Polymer Sciences
Physical Chemistry
Soft Matter and Complex Fluids
Characterization and Evaluation Materials
Food Science - 出版者：Springer Berlin / Heidelberg
- ISSN：1435-1536
- 卷排序：294
文摘
The stability mechanism and thermal properties of the system alumina–anionic polyacrylamide (PAM) was studied. The polymer’s adsorption properties in dependence on the following parameters solution pH (in the range 3–9), temperature (in the range 15–35 °C), and carboxyl groups’ content in the PAM chains (in the range 5–30 %) were examined. The turbidimetry method was applied for determination of the suspension stability of alumina in the presence of PAM. The obtained results indicate that the polymer addition improves significantly Al2O3 suspension stability at pH 6 and 9 (in the whole examined temperature range). PAM containing a larger number of carboxyl groups stabilizes solid particles more effectively (due to greater contribution of electrosteric interactions). Moreover, the polymer adsorption on the alumina surface causes changes in the thermal stability of the examined systems. In dependence on temperature, the higher the content of carboxyl groups in the PAM molecules, the greater the total mass loss. This is due to increased adsorption of polyacrylamide whose chains contain numerous –COOH groups.KeywordsAnionic PAMAlumina surfaceThermogravimetric analysisTemperature effectCarboxyl groups contentElectrosteric stabilization