Formation kinetics of nanoparticles as the basis for simulating the generation mechanism of Liesegang rings in gels

详细信息    查看全文

• 作者：V. I. Kuz’min (1)
  A. F. Gadzaov (1)
  D. L. Tytik (2)
  V. V. Vysotskii (2)
  S. A. Busev (2)
  A. A. Revina (2)
  
• 刊名：Colloid Journal
• 出版年：2014
• 出版时间：July 2014
• 年：2014
• 卷：76
• 期：4
• 页码：439-446
• 全文大小：1,036 KB
• 参考文献：1. Beneke, K., / Liesegang Named in Literature (Published 1790-003), Kiel: Christian-Albrechts Univ., 2004.
  2. Shemyakin, F.M. and Mikhalev, P.F., / Fiziko-khimicheskie periodicheskie protsessy (Physicochemical Periodical Processes), Moscow: Akad. Nauk SSSR, 1938.
  3. Kuz’min, V.I., Gadzaov, A.F., Tytik, D.L., Busev, S.A., Revina, A.A., and Vysotskii, V.V., / J. Struct. Chem., 2013, vol. 54, Appl. 2, p. 368. lass="external" href="http://dx.doi.org/10.1134/S0022476613020133" target="_blank" title="It opens in new window">CrossRef
  4. Scheel, A., / Nonlinearity, 2009, vol. 22, p. 457. lass="external" href="http://dx.doi.org/10.1088/0951-7715/22/2/012" target="_blank" title="It opens in new window">CrossRef
  5. Vysotskii, V.V., Uryupina, O.Ya., Gusel’nikova, A.V., and Roldughin, V.I., / Colloid J., 2009, vol. 71, p. 739. lass="external" href="http://dx.doi.org/10.1134/S1061933X09060027" target="_blank" title="It opens in new window">CrossRef
  6. Guter, R.S., Kudryavtsev, L.D., and Levitan, B.M., / Elementy teorii funktsii. Funktsii deistvitel’nogo peremennogo. Priblizhenie funktsii. Pochti-periodicheskie funktsii (Elements of the Theory of Functions. Functions of Real Variable. Function Approximation. Quasiperiodic Functions), Moscow: Fizmatgiz, 1963.
  7. Levitan, B.M. and Zhikov, V.V., / Pochti-periodicheskie funktsii i differentsial’nye uravneniya (Quasiperiodic Functions and Differential Equations), Moscow: Mosk. Gos. Univ., 1978.
  8. Johnson, M.O., / Correlations of Cycles in Weather, Solar Activity, Geomagnetic Values and Planetary Configurations, San Francisco: Phillips and Van Orden, 1946.
  9. Kuz’min, V.I. and Gadzaov, A.F., / Metody postroeniya modelei po empiricheskim dannym (Methods of Model Construction with the Empirical Data), Moscow: MGTU MIREA, 2012.
  10. Kuz’min, V.I., Gadzaov, A.F., Tytik, D.L., Belashchenko, D.K., and Sirenko, A.N., / Nanotechnol. Russ., 2010, vol. 5, p. 800. lass="external" href="http://dx.doi.org/10.1134/S199507801011008X" target="_blank" title="It opens in new window">CrossRef
  11. Bondarenko, V.A., Mitrikas, V.G., Nosovskii, A.M., Tsetlin, V.V., Kuz’min, V.I., Gadzaov, A.F., and Tytik, D.L., / Biomed. Radioelektron., 2011, no. 11, p. 34.
  12. / Liquid Propellant Rocket Combustion Instability, D. Harrje and F. Reardon, Eds., Washington: NASA,1972.
  
• 作者单位：V. I. Kuz’min (1)
  A. F. Gadzaov (1)
  D. L. Tytik (2)
  V. V. Vysotskii (2)
  S. A. Busev (2)
  A. A. Revina (2)
  
  1. Moscow State Technical University of Radio Engineering, Electronics, and Automation, pr. Vernadskogo 78, Moscow, 119454, Russia
  2. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119991, Russia
  
• ISSN：1608-3067

文摘

An approach has been proposed for determining the space-time parameters of the formation process of Liesegang rings. This approach relates the processes of the formation of nanoparticles and dense periodic precipitates from them. Dynamic light scattering is employed to reveal periodic variations in the intensity of light scattered by nanoparticles with different sizes, from which Liesegang rings are formed. A relationship between the periods of the variations in the intensity of light scattered by nanoparticles (microscopic process) and the times of the formation of Liesegang rings as a whole (macroscopic process) has been found.