Effect of polyene chain length on the parameters of intra- and intermolecular interactions between all-trans diphenyl polyenes

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• 作者：V. V. Kompaneez ; I. A. Vasilieva
• 刊名：Bulletin of the Russian Academy of Sciences: Physics
• 出版年：2016
• 出版时间：July 2016
• 年：2016
• 卷：80
• 期：7
• 页码：848-854
• 全文大小：679 KB
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• 作者单位：V. V. Kompaneez (1)
  I. A. Vasilieva (1)
  
  1. Moscow State Pedagogical University, Moscow, 119571, Russia
  
• 刊物类别：Physics and Astronomy
• 刊物主题：Physics
  Nuclear Physics, Heavy Ions and Hadrons
  Russian Library of Science
  
• 出版者：Allerton Press, Inc. distributed exclusively by Springer Science+Business Media LLC
• ISSN：1934-9432
• 卷排序：80

文摘

The parameters of Franck–Condon and Herzberg–Teller interactions that form the fine-structure spectra of all-trans diphenyl polyenes in n-paraffin solutions at 4.2 K are analyzed. The effect the length of a polyene chain has on the emergence of benzene fragment bands is considered for four all-trans-diphenyl polyene compounds that differ by the number of π-conjugated bonds in the polyene chain. Original Russian Text © V.V. Kompaneez, I.A. Vasilieva, 2016, published in Izvestiya Rossiiskoi Akademii Nauk. Seriya Fizicheskaya, 2016, Vol. 80, No. 7, pp. 927–933.