Identification of aroma compounds and precursors of sour guava (Psidium friedrichsthalianum Nied.) following a sensomics approach

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• 作者：Carmen Tatiana Cuadrado-Silva…
• 关键词：Myrtaceae ; Odour ; active volatiles ; Glycosidic aroma precursors ; Cysteine ; S ; conjugates ; AEDA
• 刊名：European Food Research and Technology
• 出版年：2017
• 出版时间：January 2017
• 年：2017
• 卷：243
• 期：1
• 页码：1-10
• 全文大小：
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Food Science; Analytical Chemistry; Biotechnology; Agriculture; Forestry;
• 出版者：Springer Berlin Heidelberg
• ISSN：1438-2385
• 卷排序：243

文摘

In this work, a sensomics approach was followed to determine the chemical constituents responsible for sour guava (Psidium friedrichsthalianum Nied.) aroma. The odour-active volatiles were isolated by solvent-assisted flavour evaporation (SAFE) with dichloromethane. By application of the aroma extract dilution analysis (AEDA), ethyl butanoate and ethyl hexanoate, 3-sulphanylhexyl acetate (sulphury), and δ-dodecalactone (fruity) were identified with the highest flavour dilution factors among the 18 odour-active compounds. Quantitative measurements performed with the internal standard method allowed to calculate the odour activity values and revealed the important role of ethyl butanoate, (Z)-3-hexenal, and ethyl hexanoate as key aroma compounds in this fruit. The sulphur compounds, dimethyl disulphide, 2-methyl-1,3-dithiolane, methional, 3-sulphanylhexyl acetate, 3-sulphanyl-1-hexanol, and bis(methylthio)methane, are reported here as sensory relevant odorants to the flavour of this fruit. The role of hexyl-β-l-glucopyranoside and 3-(1-hexanol)-l-cysteine as precursors of hexanol, and 3-sulphanyl hexanol, respectively, was demonstrated by enzymatic hydrolysis of corresponding precursor mixtures.