Electronic Structure, Aromaticity, and Physicochemical Characteristics of Carbene, Radical, and Ionic Forms of Compounds of the Imidazole Series, and their Oxo and Thio Analogs

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• 作者：Yu. B. Vysotsky ; V. S. Bryantsev and O. A. Gorban
• 关键词：carbenes ; aromaticity ; diamagnetic susceptibility ; chemical shifts ; electronic structure ; electronic spectra
• 刊名：Chemistry of Heterocyclic Compounds
• 出版年：2002
• 出版时间：2002
• 年：2002
• 卷：38
• 期：12
• 页码：1451-1468
• 全文大小：194 KB
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry<br>Organic Chemistry<br>Pharmacy<br>Russian Library of Science<br>
• 出版者：Springer New York
• ISSN：1573-8353

文摘

The effects of benzannellation, phenyl substitution at the nitrogen atom, protonation at the carbene carbon, ionization, and the state of the carbene center (2 or 2) on the electronic structure, diamagnetic susceptibility, induced -electron ring currents, the 1H, 13C, and 14N chemical shifts, and the energies of the lowest electronic transitions of imidazol-2-ylidenes and their oxo and thio analogs were examined in the bound version of -electron perturbation theory. The calculated and experimental data are compared.