Statistical Optimization of Ethanol-Based Biodiesel Production from Sludge Palm Oil Using Locally Produced Candida cylindracea Lipase

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• 作者：Ricca Rahman Nasaruddin ; Md Zahangir Alam…
• 关键词：Biodiesel ; Free fatty acid ; Lipase ; Optimization ; Sludge palm oil
• 刊名：Waste and Biomass Valorization
• 出版年：2016
• 出版时间：February 2016
• 年：2016
• 卷：7
• 期：1
• 页码：87-95
• 全文大小：565 KB
• 参考文献：1.Bajaj, A., Lohan, P., Jha, P.N., Mehrotra, R.: Biodiesel production through lipase catalyzed transesterification: an overview. J. Mol. Catal. B Enzym. 62, 9–14 (2010)CrossRef
  2.Atadashi, I.M., Aroua, M.K., Abdul Aziz, A.R., Sulaiman, N.M.N.: High quality biodiesel obtained through membrane technology. J. Membr. Sci. 421/422, 154–164 (2012)CrossRef
  3.Wang, Y., Wang, X., Liu, Y., Ou, S., Tan, Y., Tang, S.: Refining of biodiesel by ceramic membrane separation. Fuel Process. Technol. 90, 422–427 (2009)CrossRef
  4.Moser, B.R.: Influence of blending canola, palm, soybean, and sunflower oil methyl esters on fuel properties of biodiesel. Energy Fuels 22, 4301–4306 (2008)CrossRef
  5.Felizardo, P., Neiva Correia, M.J., Raposo, I., Mendes, J.F., Berkemeier, R., Bordado, J.M.: Production of biodiesel from waste frying oils. Waste Manag. 26, 487–494 (2006)CrossRef
  6.Chongkhong, S., Tongurai, C., Chetpattananondh, P.: Continuous esterification for biodiesel production from palm fatty acid distillate using economical process. Renew. Energy 34, 1059–1063 (2009)CrossRef
  7.Ghadge, S.V., Raheman, H.: Biodiesel production from mahua (Madhucaindica) oil having high free fatty acids. Biomass Bioenergy 28, 601–605 (2005)CrossRef
  8.Sahoo, P.K., Das, L.M., Babu, M.K.G., Naik, S.N.: Biodiesel development from high acid value polanga seed oil and performance evaluation in a CI engine. Fuel 86, 448–454 (2007)CrossRef
  9.Veljkovic, V.B., Lakicevic, S.H., Stamenkovic, O.S., Todorovic, Z.B., Lazic, M.L.: Biodiesel production from tobacco (Nicotianatabacum L.) seed oil with a high content of free fatty acids: short communication. Fuel 85, 2671–2675 (2006)CrossRef
  10.Encinar, J.M., Sánchez, N., Martínez, G., García, L.: Study of biodiesel production from animal fats with high free fatty acid content. Bioresour. Technol. 102(23), 10907–10914 (2011)CrossRef
  11.Hayyan, A., Alam, M.Z., Kabbashi, N.A., Mirghani, M.E.S., Hakimi, N.I.N.M., Siran, Y.M., Tahiruddin, S.: Sludge palm oil as a renewable raw material for biodiesel production by two-step processes. Bioresour. Technol. 101, 7804–7811 (2010)CrossRef
  12.Hayyan, A., Alam, M.Z., Kabbashi, N.A., Mirghani, M.E.S., Hakimi, N.I.N.M., Siran, Y.M., Tahiruddin, S.: Reduction of high content of free fatty acid in sludge palm oil via acid catalyst for biodiesel production. Fuel Process. Technol. 92, 920–924 (2011)CrossRef
  13.Nasaruddin, R.R., Alam, M.Z., Jami, M.S.: Evaluation of solvent system for the enzymatic synthesis of ethanol-based biodiesel from sludge palm oil (SPO). Bioresour. Technol. 154, 155–161 (2014)CrossRef
  14.Wafti, N.A., Harrison, L.L.N., Choo, Y.M.: Value-added products from palm sludge oil. J. Appl. Sci. 12(11), 1199–1202 (2012)CrossRef
  15.Tongboriboon, K., Cheirsilp, B., H-Kittikun, A.: Mixed lipases for efficient enzymatic synthesis of biodiesel from used palm oil and ethanol in a solvent-free system. J. Mol. Catal. B Enzym. 67, 52–59 (2010)CrossRef
  16.Li, Q., Xu, J., Du, W., Li, Y., Liu, D.: Ethanol: as the acyl acceptor for biodiesel production. Renew. Sustain. Energy Rev. 25, 742–748 (2013)CrossRef
  17.Noureddini, H., Gao, X., Philkana, R.S.: Immobilized Pseudomonas cepacia lipase for biodiesel fuel production from soybean oil. Bioresour. Technol. 96, 769–777 (2005)CrossRef
  18.Ren, H., Du, W., Lv, L., Liu, D.: Study on free lipase-catalyzed ethanolysis for biodiesel preparation in an oil/water biphasic system. J. Am. Oil Chem. Soc. 88, 1551–1555 (2011)CrossRef
  19.Rosset, I.G., Tavares, M.C.H., Assaf, E.M., Porto, A.L.M.: Catalytic ethanolysis of soybean oil with immobilized lipase from Candida antarctica and 1H NMR and GC quantification of the ethyl esters (biodiesel) produced. Appl. Catal. A Gen. 392, 136–142 (2011)CrossRef
  20.Rosset, I.G., Assaf, E.M., Porto, A.L.M.: Biocatalytic production of ethyl esters (biodiesel) by enzymatic trans-esterification from synthetic triolein. Current Catal. 2, 53–61 (2013)CrossRef
  21.Rosset, I.G., Cavalheiro, M.C.H.T., Assaf, E.M., Porto, A.L.M.: Enzymatic esterification of oleic acid with aliphatic alcohols for the biodiesel production by Candida antarctica lipase. Catal. Lett. 143, 863–872 (2013)CrossRef
  22.Moreira, A.B.R., Perez, V.H., Zanin, G.M., Castro, H.F.D.: Biodiesel synthesis by enzymatic transesterification of palm oil with ethanol using lipases from several sources immobilized on silica–PVA composite. Energy Fuels 21, 3689–3694 (2007)CrossRef
  23.Salihu, A., Alam, M.Z., AbdulKarim, M.I., Salleh, H.M.: Optimization of lipase production by Candida cylindracea in palm oil mill effluent based medium using statistical experimental design. J. Mol. Catal. B Enzym. 69, 66–73 (2011)CrossRef
  24.Gopinath, S.C.B., Anbu, P., Hilda, A.: Extracellular enzymatic activity profiles in fungi isolated from oil-rich environments. Mycoscience 46, 119–126 (2005)CrossRef
  25.Ainie, K., Siew, W.L., Tan, Y.A., Nor Aini, I., Mohtar, Y., Tang, T.S., Nuzul, A.I.: MPOB Test Methods. Malaysian Palm Oil Board, Malaysia (2005)
  26.Nasaruddin, R.R., Alam, M.Z., Jami, M.S.: Enzymatic biodiesel production from sludge palm oil (SPO) using locally produced Candida cylindracealipase. Afr. J. Biotechnol. 12(31), 4966–4974 (2013)CrossRef
  27.Yücel, Y.: Optimization of biocatalytic biodiesel production from pomace oil using response surface methodology. Fuel Process. Technol. 99, 97–102 (2012)CrossRef
  28.Tan, T., Lu, J., Nie, K., Deng, L., Wang, F.: Biodiesel production with immobilized lipase: a review. Biotechnol. Adv. 28, 628–634 (2010)CrossRef
  29.Wan Omar, W.N.N., Amin, A.S.: Optimization of heterogeneous biodiesel production from waste cooking palm oil via response surface methodology. Biomass Bioenergy 35, 1329–1338 (2011)CrossRef
  30.Hsu, A.F., Jones, K., Marmer, W.N., Foglia, T.A.: Production of alkyl esters from tallow and grease using lipase immobilized in a phyllosilicate sol–gel. J. Am. Oil Chem. Soc. 78(6), 585–588 (2001)CrossRef
  31.Chen, J.-W., Wu, W.-T.: Regeneration of immobilized Candida antarctica lipase for transesterification. J. Biosci. Bioeng. 95, 466–469 (2003)CrossRef
  32.Christopher, L.P., Kumar, H., Zambare, V.P.: Enzymatic biodiesel: challenges and opportunities. Appl. Energy 119, 497–520 (2014)CrossRef
  33.Yusoff, M.F.M., Xu, X., Guo, Z.: Comparison of fatty acid methyl and ethyl esters as biodiesel base stock: a review on processing and production requirements. J. Am. Oil Chem. Soc. 91, 525–531 (2014)CrossRef
  
• 作者单位：Ricca Rahman Nasaruddin (1)
  Md Zahangir Alam (1)
  Mohammed Saedi Jami (1)
  Aliyu Salihu (1) (2)
  
  1. Department of Biotechnology Engineering, Faculty of Engineering, Bioenvironmental Engineering Research Centre (BERC), International Islamic University Malaysia, 50728, Kuala Lumpur, Malaysia
  2. Department of Biochemistry, Ahmadu Bello University, Zaria, Nigeria
  
• 刊物类别：Engineering
• 刊物主题：Engineering, general
  Environment
  Waste Management and Waste Technology
  Industrial Pollution Prevention
  Renewable and Green Energy
  Environmental Engineering
  
• 出版者：Springer Netherlands
• ISSN：1877-265X

文摘

Face centered central composite design was used to optimize the enzyme loading, reaction temperature and mixing speed of sludge palm oil (SPO) transesterification reaction using locally produced Candida cylindracea lipase. The developed quadratic model was found to be significant at p < 0.05. The highest biodiesel yield of 57.5 % (w/w SPO) and 15.22 % free fatty acids (FFA) conversion to biodiesel with coefficient of determination R2 of 0.91 and 0.93, respectively were obtained at enzyme loading of 0.4 U/g SPO, 41 °C and 250 rpm mixing speed. Enzyme loading (U/g) gave little effect on the %FFA conversion to biodiesel and total biodiesel yield compared to temperature and mixing speed due to high FFA and water content, thus further studies are required for improvement. The study shows the low cost SPO and locally produced lipase have a promising potential in the utilization of waste for low cost biodiesel production. Keywords Biodiesel Free fatty acid Lipase Optimization Sludge palm oil