Photocatalytic H2 Production from Ethanol–Water Mixtures Over Pt/TiO2 and Au/TiO2 Photocatalysts: A Comparative Study
详细信息 查看全文
- 作者：Vedran Jovic (1)
Zakiya H. N. Al-Azri (1)
Wan-Ting Chen (1)
Dongxiao Sun-Waterhouse (1)
H. Idriss (2) (3)
Geoffrey I. N. Waterhouse (1) - 关键词：Photocatalysis ; Hydrogen production ; Titania ; Platinum ; Gold ; Ethanol
- 刊名：Topics in Catalysis
- 出版年：2013
- 出版时间：August 2013
- 年：2013
- 卷：56
- 期：12
- 页码：1139-1151
- 全文大小：874KB
- 参考文献：1. Chiarello GL, Selli E (2010) Recent Pat Eng 3:155-69 nal" href="http://dx.doi.org/10.2174/187221210794578600">CrossRef
2. Navarro RM, Pe?a MA, Fierro JL (2007) Chem Rev 10:3952-991 nal" href="http://dx.doi.org/10.1021/cr0501994">CrossRef
3. Waterhouse GIN, Idriss H (2009) In: Vayssieres L (ed) On solar hydrogen and nanotechnology. Wiley, Chichester
4. Ni M, Leung MKH, Leung DYC, Sumathy K (2007) Renew Sustain Energy Rev 3:401-25 nal" href="http://dx.doi.org/10.1016/j.rser.2005.01.009">CrossRef
5. Matsuoka M, Kitano M, Takeuchi M, Tsujimaru K, Anpo M, Thomas JM (2007) Catal Today 1-:51-1 nal" href="http://dx.doi.org/10.1016/j.cattod.2007.01.042">CrossRef
6. Shimura K, Yoshida H (2011) Energy Environ Sci 7:2467-481 nal" href="http://dx.doi.org/10.1039/c1ee01120k">CrossRef
7. Rajeshwar K (2007) J Appl Electrochem 7:765-87 nal" href="http://dx.doi.org/10.1007/s10800-007-9333-1">CrossRef
8. Linsebigler AL, Lu G, Yates JT (1995) Chem Rev 3:735-58 nal" href="http://dx.doi.org/10.1021/cr00035a013">CrossRef
9. Fujishima A, Rao TN, Tryk DA (2000) J Photochem Photobiol C 1:1-1 nal" href="http://dx.doi.org/10.1016/S1389-5567(00)00002-2">CrossRef
10. Bamwenda GR, Tsubota S, Nakamura T, Haruta M (1995) J Photochem Photobiol A 2:177-89 nal" href="http://dx.doi.org/10.1016/1010-6030(95)04039-I">CrossRef
11. Nadeem MA, Murdoch M, Waterhouse GIN, Metson JB, Keane MA, Llorca J, Idriss H (2010) J Photochem Photobiol A 2-:250-55 nal" href="http://dx.doi.org/10.1016/j.jphotochem.2010.07.007">CrossRef
12. Yu J, Hai Y, Jaroniec M (2011) J Colloid Interface Sci 1:223-28 nal" href="http://dx.doi.org/10.1016/j.jcis.2011.01.101">CrossRef
13. Cheng P, Yang Z, Wang H, Cheng W, Chen M, Shangguan W, Ding G (2012) Int J Hydrogen Energy 3:2224-230 nal" href="http://dx.doi.org/10.1016/j.ijhydene.2011.11.004">CrossRef
14. Park HG, Holt JK (2010) Energy Environ Sci 8:1028-036 nal" href="http://dx.doi.org/10.1039/b922057g">CrossRef
15. Murdoch M, Waterhouse GIN, Nadeem MA, Metson JB, Keane MA, Howe RF, Llorca J, Idriss H (2011) Nat Chem 6:489-92
16. Chiarello GL, Selli E, Forni L (2008) Appl Catal B 1-:332-39
17. Subramanian V, Wolf EE, Kamat PV (2004) J Am Chem Soc 15:4943-950 nal" href="http://dx.doi.org/10.1021/ja0315199">CrossRef
18. Kamat PV (2008) J Phys Chem C 48:18737-8753
19. Waterhouse GIN, Murdoch M, Llorca J, Idriss H (2012) Int J Nanotechnol 1:113-20 nal" href="http://dx.doi.org/10.1504/IJNT.2012.044832">CrossRef
20. Bickley RI, Gonzalez-Carreno T, Lees JS, Palmisano L, Tilley RJD (1991) J Solid State Chem 1:178-90 nal" href="http://dx.doi.org/10.1016/0022-4596(91)90255-G">CrossRef
21. Datye AK, Riegel G, Bolton JR, Huang M, Prairie MR (1995) J Solid State Chem 1:236-39 nal" href="http://dx.doi.org/10.1006/jssc.1995.1126">CrossRef
22. Ohno T, Sarukawa K, Tokieda K, Matsumura M (2001) J Catal 1:82-6 nal" href="http://dx.doi.org/10.1006/jcat.2001.3316">CrossRef
23. Ohtani B, Prieto-Mahaney OO, Li D, Abe R (2010) J Photochem Photobiol A 2-:179-82 nal" href="http://dx.doi.org/10.1016/j.jphotochem.2010.07.024">CrossRef
24. Hurum DC, Agrios AG, Gray KA, Rajh T, Thurnauer MC (2003) J Phys Chem B 19:4545-549 nal" href="http://dx.doi.org/10.1021/jp0273934">CrossRef
25. Haruta M (1997) Catal Surv Jpn 1:61-3 nal" href="http://dx.doi.org/10.1023/A:1019068728295">CrossRef
26. Pichat P, Mozzanega M-N, Courbon H (1987) J Chem Soc Farad Trans 1(3):697-04
27. Lin CH, Lee CH, Chao JH, Kuo CY, Cheng YC, Huang WN, Chang HW, Huang YM, Shih MK (2004) Catal Lett 1:61-6 nal" href="http://dx.doi.org/10.1007/s10562-004-6450-x">CrossRef
28. Gallo A, Montini T, Marelli M, Minguzzi A, Gombac V, Psaro R, Fornasiero P, Dal Santo V (2012) ChemSusChem 9:1800-811 nal" href="http://dx.doi.org/10.1002/cssc.201200085">CrossRef
29. Zanella R, Giorgio S, Henry CR, Louis C (2002) J Phys Chem B 31:7634-642 nal" href="http://dx.doi.org/10.1021/jp0144810">CrossRef
30. Alonso F, Riente P, Rodríguez-Reinoso F, Ruiz-Martínez J, Sepúlveda-Escribano A, Yus M (2008) J Catal 1:113-18 nal" href="http://dx.doi.org/10.1016/j.jcat.2008.09.009">CrossRef
31. Huang B-S, Chang F-Y, Wey M-Y (2010) Int J Hydrogen Energy 15:7699-705 nal" href="http://dx.doi.org/10.1016/j.ijhydene.2010.05.103">CrossRef
32. Fu X, Clark LA, Yang Q, Anderson MA (1996) Environ Sci Technol 2:647-53 nal" href="http://dx.doi.org/10.1021/es950391v">CrossRef
33. Kimura K, Naya S-i, Jin-nouchi Y, Tada H (2012) J Phys Chem C 12:7111-117 nal" href="http://dx.doi.org/10.1021/jp301681n">CrossRef
34. Kowalska E, Mahaney OOP, Abe R, Ohtani B (2010) Phys Chem Chem Phys 10:2344-355 nal" href="http://dx.doi.org/10.1039/b917399d">CrossRef
35. Chen J-J, Wu JCS, Wu PC, Tsai DP (2010) J Phys Chem C 1:210-16
36. Tanaka A, Sakaguchi S, Hashimoto K, Kominami H (2012) ACS Catal 1:79-5
37. Rosseler O, Shankar MV, Du MK-L, Schmidlin L, Keller N, Keller V (2010) J Catal 1:179-90 nal" href="http://dx.doi.org/10.1016/j.jcat.2009.11.006">CrossRef
38. Li XZ, Li FB (2001) Environ Sci Technol 11:2381-387 nal" href="http://dx.doi.org/10.1021/es001752w">CrossRef
39. Cárdenas-Lizana F, Gómez-Quero S, Idriss H, Keane MA (2009) J Catal 2:223-34 nal" href="http://dx.doi.org/10.1016/j.jcat.2009.09.020">CrossRef
40. Howard A, Clark DNS, Mitchell CEJ, Egdell RG, Dhanak VR (2002) Surf Sci 3:210-24 nal" href="http://dx.doi.org/10.1016/S0039-6028(02)02124-6">CrossRef
41. Idriss H, Barteau MA (1992) J Phys Chem 96:3382-388 nal" href="http://dx.doi.org/10.1021/j100187a037">CrossRef
42. Jing L, Qu Y, Wang B, Li S, Jiang B, Yang L, Fu W, Fu H, Sun J (2006) Sol Energy Mater Sol Cells 90:1773-787 nal" href="http://dx.doi.org/10.1016/j.solmat.2005.11.007">CrossRef
43. Vazquez LN Master in photonics Experimental setup fopr carrier lifetime measurement based on photoluminescence response. Escole Tecnica Superior, Universtat Politècnica de Catalunya (UPC)
44. Lunawat P, Kumar R, Gupta N (2008) Catal Lett 3-:226-33 nal" href="http://dx.doi.org/10.1007/s10562-007-9319-y">CrossRef
45. Serpone N, Lawless D, Khairutdinov R (1995) J Phys Chem 45:16646-6654 nal" href="http://dx.doi.org/10.1021/j100045a026">CrossRef
46. Abazovi? ND, ?omor MI, Drami?anin MD, Jovanovi? DJ, Ahrenkiel SP, Nedeljkovi? JM (2006) J Phys Chem B 50:25366-5370 nal" href="http://dx.doi.org/10.1021/jp064454f">CrossRef
47. Daude N, Gout C, Jouanin C (1977) Phys Rev B 6:3229-235 nal" href="http://dx.doi.org/10.1103/PhysRevB.15.3229">CrossRef
48. Nakajima H, Mori T, Watanabe M (2004) J Appl Phys 1:925-27 nal" href="http://dx.doi.org/10.1063/1.1757649">CrossRef
49. Nakajima H, Mori T (2006) Physica B 376-77:820-22 nal" href="http://dx.doi.org/10.1016/j.physb.2005.12.205">CrossRef
50. Sakata T, Kawai T (1981) Chem Phys Lett 2:341-44 nal" href="http://dx.doi.org/10.1016/0009-2614(81)80121-2">CrossRef
51. Bowker M, Millard L, Greaves J, James D, Soares J (2004) Gold Bull 37:170-73 nal" href="http://dx.doi.org/10.1007/BF03215209">CrossRef
52. Xu M, Gao Y, Moreno EM, Kunst M, Muhler M, Wang Y, Idriss H, W?ll C (2011) Phys Rev Lett 13:138302 nal" href="http://dx.doi.org/10.1103/PhysRevLett.106.138302">CrossRef
53. Connelly K, Wahab AK, Idriss H (2012) Mater Renew Sustain Energy 1:1-2 nal" href="http://dx.doi.org/10.1007/s40243-012-0003-9">CrossRef
54. Bowker M (2011) Green Chem 9:2235-246 nal" href="http://dx.doi.org/10.1039/c1gc00022e">CrossRef
55. Pichat P, Herrmann JM, Disdier J, Mozzanega MN, Courbon H (1984) Stud Surf Sci Catal 19:319-26 nal" href="http://dx.doi.org/10.1016/S0167-2991(09)60114-2">CrossRef
56. Nardelli MB, Rapcewicz K, Bernholc J (1997) Appl Phys Lett 21:3135-137 nal" href="http://dx.doi.org/10.1063/1.120269">CrossRef
57. Linic S, Christopher P, Ingram DB (2011) Nat Mater 12:911-21 nal" href="http://dx.doi.org/10.1038/nmat3151">CrossRef - 作者单位：Vedran Jovic (1)
Zakiya H. N. Al-Azri (1)
Wan-Ting Chen (1)
Dongxiao Sun-Waterhouse (1)
H. Idriss (2) (3)
Geoffrey I. N. Waterhouse (1)
1. School of Chemical Sciences, The University of Auckland, Private Bag 92019, Auckland, New Zealand
2. SABIC Research Centres, Riyadh, Saudi Arabia
3. KAUST, Thuwal, Saudi Arabia - ISSN：1572-9028
文摘
Pt/TiO2 (Pt loadings 0-?wt%) and Au/TiO2 (Au loadings 0-?wt%) photocatalysts were synthesized, characterized and tested for H2 production from ethanol–water mixtures (80?vol% ethanol, 20?vol% H2O) under UV excitation. Average metal nanoparticle sizes determined by TEM were 1-?nm for Pt in the Pt/TiO2 photocatalysts and 5-?nm for Au in the Au/TiO2 photocatalysts. Au/TiO2 showed an intense localized surface plasmon resonance feature at ~570?nm, typical for metallic Au nanoparticles of diameter ~5?nm supported on TiO2. X-ray photoelectron spectroscopy and X-ray diffraction analyses established that Pt and Au were present in metallic form on the TiO2 support. X-ray fluorescence revealed close accord between nominal and actual Pt and Au loadings. The Au/TiO2 and Pt/TiO2 photocatalysts both displayed very high activities for H2 production under UV irradiation, with the Au/TiO2 samples affording slightly superior rates of H2 production at most metal loadings. The 2?wt% Au/TiO2 and 1?wt% Pt/TiO2 photocatalysts showed the highest H2 production rates (32-4 mmol?g??h?). Photoluminescence studies confirmed that Pt and Au nanoparticles positively enhance the photocatalytic properties of P25 TiO2 for H2 production by acting as electron acceptors and thereby suppressing electron–hole pair recombination in TiO2.