As(III) Adsorption and Oxidation by Metal (Hydro) Oxides Enriched on Alligator Weed Root
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  • 作者:Jian Chen ; Weihua Tao ; Cheng Sun
  • 关键词:Alligator weed root ; Metal (hydro) oxide ; As(III) ; Adsorption ; Oxidation
  • 刊名:Water, Air, and Soil Pollution
  • 出版年:2015
  • 出版时间:October 2015
  • 年:2015
  • 卷:226
  • 期:10
  • 全文大小:849 KB
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  • 作者单位:Jian Chen (1) (2) (3)
    Weihua Tao (2) (3)
    Cheng Sun (1)

    1. The State Key Laboratory of Pollution Control and Resource Reuse, School of the Environment, Nanjing University, Nanjing, 210023, People鈥檚 Republic of China
    2. Jiangsu Provincial Key Laboratory of Coastal Wetland Bioresources and Environmental Protection, Yancheng Teachers University, Xiwang Road, Yancheng, Jiangsu, 224051, People鈥檚 Republic of China
    3. School of Chemistry and Engineering, Yancheng Teachers University, Xiwang Road, Yancheng, Jiangsu, 224051, People鈥檚 Republic of China
  • 刊物类别:Earth and Environmental Science
  • 刊物主题:Environment
    Environment
    Atmospheric Protection, Air Quality Control and Air Pollution
    Waste Water Technology, Water Pollution Control, Water Management and Aquatic Pollution
    Terrestrial Pollution
    Hydrogeology
  • 出版者:Springer Netherlands
  • ISSN:1573-2932
文摘
The dried powder of the alligator weed root (AWR) was employed as a biosorbent to remove As(III) from aqueous solution, using acid pre-treated AWR (HAWR) and As(V) as the contrasts. The results of batch adsorption experiment suggested that there is no substantial difference between As(III) and As(V) adsorption. Both of them are affected by the solution pH significantly, but insensitive to the ionic strength. The speciation analysis indicated that more than 95 % of the total As(III) in aqueous solution is oxidized into As(V) in the presence of AWR, while barely oxidized in the presence of HAWR. It proves that without pre-oxidation, AWR can oxidize and adsorb As(III), simultaneously. The properties of the biosorbent were characterized by various techniques including scanning electronic microscopy-energy dispersive spectrometer, Fourier transform infrared spectra analysis, inductive coupled plasma emission spectrometer and Zeta potential detection. The results suggested that typical metals including Mn, Fe and Al enrich in the morphology of metal (hydro) oxide over the surface of AWR, originally. Based on the nature of the biosorbent and arsenic besides the adsorption and oxidation performances, the metal (hydro) oxides are proved as the essential role to drive the adsorption and oxidation. The proof is that with the metal (hydro) oxides denuded, as the contrast of AWR, HAWR loses its capability of adsorption and oxidation for As(III), totally. Keywords Alligator weed root Metal (hydro) oxide As(III) Adsorption Oxidation

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