Laser Direct Writing of Conductive Silver Micropatterns on Transparent Flexible Double-Decker-Shaped Polysilsesquioxane Film Using Silver Nanoparticle Ink

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• 作者：Mohammod Aminuzzaman ; Akira Watanabe ; Tokuji Miyashita
• 关键词：Printed electronics ; laser direct writing ; micropatterns ; nanometal ink ; hybrid polymer ; double ; decker ; shaped polysilsesquioxane (DDPSQ)
• 刊名：Journal of Electronic Materials
• 出版年：2015
• 出版时间：December 2015
• 年：2015
• 卷：44
• 期：12
• 页码：4811-4818
• 全文大小：5,111 KB
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• 作者单位：Mohammod Aminuzzaman (1) (2)
  Akira Watanabe (1)
  Tokuji Miyashita (1)
  
  1. Institute of Multidisciplinary Research for Advanced Materials (IMRAM), Tohoku University, Katahira 2-1-1, Aoba-ku, Sendai, 980-8577, Japan
  2. Department of Chemical Science, Faculty of Science, Peark Campus, Universiti Tunku Abdul Rahman (UTAR), Jalan Universiti, Bnadar Barat, 31900, Kamapar, Perak D. R., Malaysia
  
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Optical and Electronic Materials
  Characterization and Evaluation Materials
  Electronics, Microelectronics and Instrumentation
  Solid State Physics and Spectroscopy
  
• 出版者：Springer Boston
• ISSN：1543-186X

文摘

This paper describes fabrication of conductive, highly adhesive silver (Ag) micropatterns on transparent flexible double-decker-shaped polysilsesquioxane (DDPSQ) film by a laser direct writing technique using a precursor film prepared from liquid-dispersed Ag nanoparticles. The laser-written Ag micropatterns have been characterized by optical microscopy, field-emission scanning electron microscopy, surface profilometry, and resistivity measurements. The line width of the Ag micropatterns can be flexibly controlled by changing the objective lens magnification and laser spot size. Using a ×100 objective lens and laser energy density of 170.50 kW/cm2, Ag micropatterns with line width of about 4 μm have been achieved. The Ag micropatterns show excellent adherence to the DDPSQ surface as evaluated by Scotch-tape test. The resistivity of the Ag micropatterns has been determined to be 4.1 × 10? Ω cm using the two-point probe method, being almost comparable to that of bulk Ag (1.6 × 10? Ω cm). Thus, high-quality, narrow, homogeneous Ag microlines with high conductivity and adhesion can be produced under optimized laser scanning conditions. Keywords Printed electronics laser direct writing micropatterns nanometal ink hybrid polymer double-decker-shaped polysilsesquioxane (DDPSQ)