Responsive polymer-based multicolor fluorescent probes for temperature and Zn2+ ions in aqueous media
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- 作者：XiangLong Hu (1)
Yang Li (1)
Tao Liu (1)
GuoYing Zhang (1)
ShiYong Liu (1) - 关键词：responsive polymers ; fluorescence ; probes ; Zn2+ ; thermometer ; multicolor transition
- 刊名：SCIENCE CHINA Chemistry
- 出版年：2014
- 出版时间：April 2014
- 年：2014
- 卷：57
- 期：4
- 页码：615-623
- 全文大小：749 KB
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Yang Li (1)
Tao Liu (1)
GuoYing Zhang (1)
ShiYong Liu (1)
1. CAS Key Laboratory of Soft Matter Chemistry; Hefei National Laboratory for Physical Sciences at the Microscale; Department of Polymer Science and Engineering, University of Science and Technology of China, Hefei, 230026, China - ISSN：1869-1870
文摘
We report on the fabrication of fluorescent and multicolor probes for Zn2+ ions and temperature from a mixture of three types of fluorophore-labeled responsive block copolymers in aqueous media. Quinoline-based Zn2+-recognizing fluorescent monomer ZQMA, red-emitting rhodamine B-based monomer RhBEA, and blue-emitting coumarin derivative Coum-OH, were synthesized first. A ZQMA-labeled well-defined double hydrophilic block copolymer (DHBC), PEG-b-P(MEO2MA-co-ZQMA), was synthesized via reversible addition-fragmentation chain-transfer (RAFT) polymerization of 2-(2-methoxyethoxy)ethyl methacrylate (MEO2MA) and ZQMA by utilizing a PEG-based macroRAFT agent. Following similar procedures, PEG-b-P(St-co-RhBEA) amphiphilic diblock copolymer and PEG-b-P(MEO2MA-co-Coum) DHBC were also synthesized, where P(St-co-RhBEA) was a RhBEA-labeled polystyrene (PS) block. At room temperature in aqueous solution, almost nonfluorescent PEG-b-P(MEO2MA-co-ZQMA) can effectively bind Zn2+ ions, leading to prominent green fluorescence enhancement due to the coordination of ZQMA with Zn2+ ions. However, by mixing red-emitting PEG-b-P(St-co-RhBEA) and blue-emitting PEG-b-P(MEO2MA-co-Coum) with PEG-b-P(MEO2MA-co-ZQMA) at an appropriate ratio, three color transitions could be observed. In the absence of Zn2+ ions, a mixed pink fluorescent originating from Coum and RhBEA was observed; upon the addition of a certain amount of Zn2+ ions, the green fluorescence enhanced dramatically, leading to a white fluorescence readout. By further increasing the amount of Zn2+ ions, the green fluorescence further enhanced and overwhelmed the blue and red emissions, leading to a green-dominant mixed-fluorescence emission. In addition, upon increasing the temperature, the fluorescence of Coum decreased considerably due to the fluorescence-resonance energy transfer (FRET) between Coum and ZQMA moieties. In this way, a ratiometric fluorescent thermometer can be constructed.