Micellar Molybdovanadophosphates Producing High Content of Carboxylic Acids from Starch Using Hydrogen Peroxide

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• 作者：Hang Wang ; Xiaoli Chen ; Lingling Zhao ; Xiaohong Wang&#8230
• 关键词：Polyoxometalates (POMs) ; Micellar heterogeneous catalyst ; Starch oxidation ; Hydrogen peroxide
• 刊名：Catalysis Surveys from Japan
• 出版年：2015
• 出版时间：September 2015
• 年：2015
• 卷：19
• 期：3
• 页码：123-128
• 全文大小：592 KB
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• 作者单位：Hang Wang (1)
  Xiaoli Chen (1)
  Lingling Zhao (1)
  Xiaohong Wang (1)
  Licheng Wang (2)
  
  1. Key Lab of Polyoxometalate Science of Ministry of Education, Faculty of Chemistry, Northeast Normal University, Changchun, 130024, People鈥檚 Republic of China
  2. Faculty of Chemistry, Jilin University, Changchun, 130000, People鈥檚 Republic of China
  
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Catalysis
  Physical Chemistry
  Industrial Chemistry and Chemical Engineering
  Characterization and Evaluation Materials
  
• 出版者：Springer Netherlands
• ISSN：1574-9266

文摘

A new kind of micellar polyoxometalate (POM) [C16H33N(CH3)3]5PV2Mo10O40 has been synthesized via ion exchange. This micellar polyoxometalate can assemble in water and concentrate substrates; resulting in higher or nearly identical performance compared to traditional catalysts, such as FeSO4. This catalyst can be easily separated from the products and its retrieved polyoxometalates can be repeatedly used without loss of performance; which highlights the application of this important biomass.