Vinylic copolymerization of norbornene and higher 1-alkene with three-dimensional geometry binickel catalyst

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• 作者：Ping Huo ; Wanyun Liu ; Xiaohui He ; Guangquan Mei
• 关键词：Binickel complex ; Addition polymerization ; B(C6F5)3 ; Cyclic olefin copolymer
• 刊名：Journal of Polymer Research
• 出版年：2015
• 出版时间：October 2015
• 年：2015
• 卷：22
• 期：10
• 全文大小：1,255 KB
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• 作者单位：Ping Huo (1)
  Wanyun Liu (1)
  Xiaohui He (2)
  Guangquan Mei (1) (3)
  
  1. Key Laboratory of Jiangxi University for Applied Chemistry and Chemical Biology, Yichun University, Yichun, 336000, China
  2. School of Materials Science and Engineering, Nanchang University, Nanchang, 330031, China
  3. State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing, 210093, China
  
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Polymer Sciences
  Industrial Chemistry and Chemical Engineering
  Characterization and Evaluation Materials
  
• 出版者：Springer Netherlands
• ISSN：1572-8935

文摘

Compared with monometallic complex, the three-dimensional geometry α-diimine binickel complex exhibited higher activities (5.5?×-05-.7?×-07 g_polymer/mol_Ni?·?h) in the homopolymerization of norbornene and copolymerization of norbornene with 1-hexene or 1-decene in the presence of B(C₆F₅)₃. The 1-hexene or 1-decene content in the copolymers could be controlled up to 9.2-5.3 % or 8.8-7.8 % by varying the comonomer feed ratios 1-hexene or 1-decene from 10 to 50 %. It was observed that the yield depended on the kind of 1-alkene and improved with increasing the length of 1-alkene. The obtained poly(NB-co-1-hexene)s and poly(NB-co-1-decene)s exhibited high thermal stability and high glass transition temperature, together with high molecular weight. In addition, copolymers showed good solubility in common organic solvents and could be processed into films by solution casting method, which showed good transparency in the visible region. Keywords Binickel complex Addition polymerization B(C₆F₅)₃ Cyclic olefin copolymer