Electrochemical synthesis of poly(3,4-ethylenedioxythiophene) doped with gold nanoparticles, and its application to nitrite sensing
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  • 作者:Peipei Lin ; Fenglian Chai ; Ruiqiao Zhang ; Guiyun Xu ; Xiaojian Fan
  • 关键词:Conducting polymer ; Nanocomposite ; Nitrite sensor ; Electropolymerization ; Cyclic voltammograms
  • 刊名:Microchimica Acta
  • 出版年:2016
  • 出版时间:March 2016
  • 年:2016
  • 卷:183
  • 期:3
  • 页码:1235-1241
  • 全文大小:963 KB
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  • 作者单位:Peipei Lin (1)
    Fenglian Chai (1)
    Ruiqiao Zhang (1)
    Guiyun Xu (1)
    Xiaojian Fan (2)
    Xiliang Luo (1)

    1. Key Laboratory of Sensor Analysis of Tumor Marker, Ministry of Education, College of Chemistry and Molecular Engineering, Qingdao University of Science and Technology, Qingdao, 266042, China
    2. Department of Breast Surgery, The Eighth Peoples’ Hospital of Qingdao, Qingdao, 266100, China
  • 刊物类别:Chemistry and Materials Science
  • 刊物主题:Chemistry
    Analytical Chemistry
    Inorganic Chemistry
    Physical Chemistry
    Characterization and Evaluation Materials
    Monitoring, Environmental Analysis and Environmental Ecotoxicology
  • 出版者:Springer Wien
  • ISSN:1436-5073
文摘
The work describes the synthesis of a nanocomposite consisting of poly(3,4-ethylenedioxythiophene) (PEDOT) doped with gold nanoparticles (AuNPs) by electropolymerization of EDOT in a solution containing colloidal AuNPs. The nanocomposite possesses good conductivity and a 3D microporous network structure owing to the presence of AuNPs. These act as both conductive dopant and template for the growth of the microporous polymer. A glassy carbon electrode modified with the nanocomposite exhibits excellent electrocatalytic activity towards oxidation of nitrite. Best operated at a voltage of 0.8 V (vs. Ag/AgCl), it is capable of detecting nitrite in the 0.2 to 1400 μM concentration range, with a detection limit of 60 nM.

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