Heavy main-group iodometallates hybridized by alkali metal via 1,10-Phenanthroline-5,6-dione

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• 作者：MENGFAN YIN ; GENGXING CAI ; PENG WANG ; XIHUI CHAO ; JIBO LIU…
• 关键词：Inorganic/organic hybrid ; main group chemistry ; iodometallate hybrid ; luminescence
• 刊名：Journal of Chemical Sciences
• 出版年：2015
• 出版时间：September 2015
• 年：2015
• 卷：127
• 期：9
• 页码：1531-1538
• 全文大小：1,076 KB
• 参考文献：1.Bi W H, Louvain N, Mercie N, Luc J, Rau I, Kajzar F and Sahraoui B 2008 Adv. Mater. 20 1013CrossRef
  2.Mercier N, Louvain N and Bi W H 2009 Cryst. Eng. Comm 11 720CrossRef
  3.Wang M S, Xu G, Zhang Z J and Guo G C 2010 Chem. Commun. 46 361CrossRef
  4.Xu G, Guo G C, Wang M S, Zhang Z J, Chen W T and Huang J S 2007 Angew. Chem. Int. Ed. 46 3249CrossRef
  5.Lin R G, Xu G, Wang M S, Lu G, Li P X and Guo G C 2013 Inorg. Chem. 52 1199CrossRef
  6.Wu L M, Wu X T and Chen L 2009 Coord. Chem. Rev. 253 2787CrossRef
  7.Kojima A, Teshima K, Shirai Y and Miyasaka T 2009 J. Am. Chem. Soc. 131 6050CrossRef
  8.Etgar L, Gao P, Xue Z S, Peng Q, Chandiran A K, Liu B, Nazeeruddin M K and Gr?tzel M 2012 J. Am. Chem. Soc. 134 17396CrossRef
  9.Jeon N J, Lee J, Noh J H, Nazeeruddin M K, Gr?tzel M and Seok S 2013 J. Am. Chem. Soc. 135 19087CrossRef
  10.Christians J A, Fung R C M and Kamat P V 2014 J. Am. Chem. Soc. 136 758CrossRef
  11.Goforth A M, Tershansy M A, Smith M D, Peterson Jr. L R, Kelley J G, DeBenedetti W J I and zur Loye H C 2011 J. Am. Chem. Soc. 133 603CrossRef
  12.Li J P, Li L H, Wu L M and Chen L 2009 Inorg. Chem. 48 1260CrossRef
  13.Leblanc N, Mercier N, Zorina L, Simonov S, Auban-Senzier P and Pasquier C 2011 J. Am. Chem. Soc. 133 14924CrossRef
  14.Chen Y, Yang Z, Guo C X, Ni C Y, Ren Z G, Li H X and Lang J P 2010 Eur. J. Inorg. Chem. 5326
  15.Krautscheid H and Vielsack F 1999 Z. Anorg. Allg. Chem. 625 562CrossRef
  16.Krautscheid H, Lode C, Vielsack F and Vollmer H 2001 J. Chem. Soc. Dalton Trans. 1099
  17.Fan L Q and Wu J H 2008 Z. Kristallogr. -New Cryst. Struct. 223 72
  18.Tershansy M A, Goforth A M, Junior L P, Burns M C, Smith M D and zur Loye H C 2007 Solid State Sci. 9 895CrossRef
  19.Burns M C, Tershansy M A, Ellsworth J M, Khaliq Z, Junior L P, Smith M D and zur Loye H C 2006 Inorg. Chem. 45 10437CrossRef
  20.Fan L Q, Wu J H and Huang Y F 2007 J. Solid State Chem. 180 3479CrossRef
  21.Wang G E, Wang M S, Zhang M J, Cai L Z, Liu B W, Zhang C J, Guo G C and Huang J S 2012 Inorg. Chem. Commun. 23 137CrossRef
  22.Chen X B, Li H H, Chen Z R, Liu J B, Li J B, Dong H J and Wu Y L 2009 J. Clust. Sci. 20 611CrossRef
  23.Li H H, Sun L G, Chen Z R, Wang Y J and Li J Q 2008 Aust. J. Chem. 61 391CrossRef
  24.Li H H, Chen Z R, Li J Q, Huang C C, Xiao G C and Zhao B 2006 J. Chem. Cryst. 36 419CrossRef
  25.Zhang Z J, Xiang S C, Zhang Y F, Wu A Q, Cai L Z, Guo G C and Huang J S 2006 Inorg.Chem. 45 1972CrossRef
  26.Zeng X H, He X, Chen J Y, Zhang J W, Li H H and Chen Z R 2014 J. Clust. Sci. 25 979CrossRef
  27.Mishra S, Jeanneau E, Iasco O, Ledoux G, Luneau D and Daniele S 2012 Eur. J. Inorg. Chem. 2749
  28.Liu J B, Li H H, Chen Z R, Guo L Q, Huang C C and Li J Q 2009 CrystEngComm 11 545CrossRef
  29.Mishra S, Jeanneau E, Daniele S, Ledoux G and Swamy P N 2008 Inorg. Chem. 47 9333CrossRef
  30.Gong A W, Wu H Y, Lian Z X, Dong H J, Li H H and Chen Z R 2013 J. Mole. Struct. 1035 109CrossRef
  31.Amghouz Z, Garcia-Granda S, Garcia J R, Ferreira R A S, Mafra L, Carlos L D and Rocha J 2011 Inorg. Chem. 51 1703CrossRef
  32.Stephenson M D, Prior T J and Hardie M J 2008 Cryst. Growth Des. 8 643CrossRef
  33.Bodige S, Torres A S, Maloney D J, Tate D, Kinsel G R, Walker A K and MacDonnell F M 1997 J. Am. Chem. Soc. 119 10364CrossRef
  34.Gaspar A B, Galet A, Munoz M C, Solans X and Real J A 2006 Inorg. Chem. 45 10431CrossRef
  35.Hiort C, Lincoln P and Norden B 1993 J. Am. Chem. Soc. 115 3448CrossRef
  36.Ma Q, Zhu M L, Yuan C X, Feng S S, Lu L P and Wang Q M 2010 Cryst. Growth Des. 10 1706CrossRef
  37.Sheldrick G M 1997 SHELXL-97, Program for X-ray Crystal Structure Refinement, University of Gottingen, Gottingen, Germany
  38.Sheldrick G M 1997 SHELXS-97, Program for X-ray Crystal Structure Solution (University of Gottingen: Gottingen, Germany)
  39.Sharma C V K, Broker G A, Huddleston J G, Baldwin J W, Metzger R M and Rogers R D 1999 J. Am. Chem. Soc. 121 1137CrossRef
  40.Mitzi D B, Medeiros D R and Malenfant P R L 2002 Inorg. Chem 41 2134CrossRef
  41.Zhang Z J, Guo G C, Xu G, Fu M L, Zou J P and Huang J S 2006 Inorg. Chem. 45 10028CrossRef
  42.Andersson S and Astron A 1972 In Solid State Chemistry, Proceedings of the 5th Materials Research Symposium (Washington DC: NBS Special Publication)
  43.Amo-Ochoa P, Jimenez-Aparicio R, Perles J, Rosario Torres M, Gennari M and Zamora F 2013 Cryst. Growth Des. 13 4977CrossRef
  44.Heller M and Sheldrick W S 2004 Z. Anorg. Allg. Chem. 630 1191CrossRef
  45.Wang S M, Mitzi D B, Feild C A and Guloy A M 1995 J. Am. Chem. Soc. 117 5297CrossRef
  46.Sourisseau S, Louvain N, Bi W, Mercier N, Rondeau D, Boucher F, Buzare J Y and Legein C 2007 Chem. Mater. 19 600CrossRef
  47.Zhu X H, Mercier N, Frere P, Blanchard P, Roncali J, Allain M, Pasquier C and Riou A 2003 Inorg. Chem. 42 5330CrossRef
  48.Wendlandt W W and Hecht H G 1966 In Reflectance Spectroscopy (New York: Interscience P
• 作者单位：MENGFAN YIN (1)
  GENGXING CAI (1)
  PENG WANG (1)
  XIHUI CHAO (1)
  JIBO LIU (1)
  HAOHONG LI (1)
  ZHIRONG CHEN (1)
  
  1. College of Chemistry, Fuzhou University, Fuzhou, Fujian, 350116, China
  
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Chemistry
  
• 出版者：Springer India
• ISSN：0973-7103

文摘

Alkali metals were introduced into heavy main-group iodometallates to get two new IA/IVAheterometallic frameworks [PbI₃K(pdon)(H₂O)₂] _n (1) and {[Pb₃ I ₉ K ₂(pdon)₂(H₃O)] ?em class="EmphasisTypeItalic ">H ₂O} _n (2) (pdon =1,10-phenanthroline-5,6-dione), which were obtained as single phases by hydrothermal method at different pH values. Compounds 1 and 2 are three-dimensional heterometallic frameworks constructed from the linkage of pdon ligand between iodometallate chains and potassium oxides/iodide clusters. Specially, these two heterometallic frameworks exhibit broadened absorption bands at 700 and 750 nm compared with those of bulk PbI₂ and pdon ligand. The band gap of 2 is wider than that of 1, which is due to the absence of π?em class="EmphasisTypeItalic ">π interaction in 2. Their thermal stabilities are also discussed.