Synthesis and electro-optical features of a high T g polymer system with excellent electro-optic activity and thermal stability

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• 作者：Rong Zhang (1) (2) (3)
  Jialei Liu (1)
  Shuhui Bo (1)
  Guowei Deng (1) (2)
  Chengcheng Peng (1) (2)
  Xinhou Liu (1)
  Zhen Zhen (1)
  
• 关键词：Second nonlinear optic ; Electro ; optic ; Chromophore ; Thermal stability
• 刊名：Colloid & Polymer Science
• 出版年：2012
• 出版时间：November 2012
• 年：2012
• 卷：290
• 期：17
• 页码：1819-1823
• 全文大小：587KB
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• 作者单位：Rong Zhang (1) (2) (3)
  Jialei Liu (1)
  Shuhui Bo (1)
  Guowei Deng (1) (2)
  Chengcheng Peng (1) (2)
  Xinhou Liu (1)
  Zhen Zhen (1)
  
  1. Key Laboratory of Photochemical Conversion and Optoelectronic Materials, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing, 100190, People’s Republic of China
  2. Graduated University of Chinese Academy of Sciences, Beijing, 100049, People’s Republic of China
  3. International Centre for Bamboo and Rattan, Beijing, 100102, People’s Republic of China
  
• ISSN：1435-1536

文摘

Three chromophores with tricyanofuran and tricyanopyrroline electron acceptors were synthesized and doped in high glass transition temperature (T g) polymer poly(N-(4-acetoxylphenyl)maleimide-co-styrene, NAPMI-co-ST). The electro-optic (EO), optical, and thermal properties of the doped poly(NAPMI-co-ST) were characterized and discussed. After being corona poled under 12?kV, this high T g polymer material showed excellent EO activity and thermal stability. The highest EO coefficient (r 33) reached 48.2?pm?V? (1,310?nm) and could remain 90?% of the original value for 100?h at 85?°C. The EO coefficient was relatively higher compared with other high T g EO polymers. The thermal stability was also very good and the manufacture process was convenient and applicable for device fabrication.