The Enthalpies of Mixing of Liquid Ni-Sn-Zn Alloys

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• 作者：Yu. Plevachuk (1)
  A. Yakymovych (2)
  S. Fürtauer (2)
  H. Ipser (2)
  H. Flandorfer (2)
  
• 关键词：calorimetry ; enthalpy of mixing ; metallic alloys ; ternary
• 刊名：Journal of Phase Equilibria and Diffusion
• 出版年：2014
• 出版时间：August 2014
• 年：2014
• 卷：35
• 期：4
• 页码：359-368
• 全文大小：607 KB
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• 作者单位：Yu. Plevachuk (1)
  A. Yakymovych (2)
  S. Fürtauer (2)
  H. Ipser (2)
  H. Flandorfer (2)
  
  1. Department of Metal Physics, Ivan Franko National University, Kyrylo and Mephodiy Str. 8, Lviv, 79005, Ukraine
  2. Department of Inorganic Chemistry (Materials Chemistry), University of Vienna, W?hringer Str. 42, 1090, Wien, Austria
  
• ISSN：1863-7345

文摘

The partial and integral enthalpies of mixing of liquid ternary Ni-Sn-Zn alloys were determined. The system was investigated along two sections x Ni/x Sn?≈?:9, x Ni/x Sn?≈?:6 at 1073?K and along two sections x Sn/x Zn?≈?:1, x Sn/x Zn?≈?:1 at 873?K. The integral enthalpy of mixing at each temperature is described using the Redlich-Kister-Muggianu model for substitutional ternary solutions. In addition, the experimental results were compared with data calculated according to the Toop extrapolation model. The minimum integral enthalpy of approx. ?0000?J?mol-1 corresponds to the minimum in the constituent binary Ni-Sn system, the maximum of approx. 3000?J?mol-1 is equal to the maximum in the binary Sn-Zn system.