Synthesis and Crystal Structure of Three New Zn(II), Ni(II) and Mn(II) Coordination Polymers Based on Asymmetric Dicarboxylate Ligand

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• 作者：Lili Yang (1) liliyang1029@yeah.net
• 关键词：Coordination polymer – ; Crystal structure – ; Asymmetric dicarboxylate
• 刊名：Journal of Inorganic and Organometallic Polymers and Materials
• 出版年：2012
• 出版时间：July 2012
• 年：2012
• 卷：22
• 期：4
• 页码：709-716
• 全文大小：672.1 KB
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• 作者单位：1. Department of Biology Chemistry Engineering, Weihai Vocational College, Weihai, 264210 Shandong, china
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Inorganic Chemistry
  Organic Chemistry
  Polymer Sciences
  
• 出版者：Springer New York
• ISSN：1574-1451

文摘

Three new coordination polymers [Zn(pda)(H₂O)]_n (1), [Ni(pda)(bib)_1.5]_n (2) and [Mn₂(pda)₂(bimb)]_n (3) [H₂pda = 3,4′-biphenyl-dicarboxylic acid, bib = 4,4′-bis (2-imidazol-1-ylmethyl) biphenyl and bmib = 4,4′-bis (2-methylimidazol-1-ylmethyl)biphenyl] have been synthesized and structurally characterized by elemental analysis, IR and X-ray diffraction. Single-crystal X-ray analyses revealed that that pda ligand acts as bridging ligand, exhibiting rich coordination modes to link metal ions: monodentate, bidentate chelating, bis-monodentate and chelating/bridging fashions. Compound 1 and 2 demonstrate a one-dimensional chain. Compound 3 is a two-dimensional (4,4) layer structure. Furthermore, the solid state luminescence spectrum of compound 1 is investigated at room temperature.