Cyclopalladated ferrocenylimines as efficient catalysts for homogeneous catalysis: A brief introduction to our preliminary achievements

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• 作者：YangJie Wu (1)
  Fan Yang (1)
  JinLi Zhang (1)
  XiuLing Cui (1)
  JunFang Gong (1)
  MaoPing Song (1)
  TieSheng Li (1)
  
• 关键词：cyclopalladated ferrocenylimine ; catalyst precursor ; coupling reaction ; homogeneous catalysis
• 刊名：Chinese Science Bulletin
• 出版年：2010
• 出版时间：September 2010
• 年：2010
• 卷：55
• 期：25
• 页码：2784-2793
• 全文大小：764KB
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• 作者单位：YangJie Wu (1)
  Fan Yang (1)
  JinLi Zhang (1)
  XiuLing Cui (1)
  JunFang Gong (1)
  MaoPing Song (1)
  TieSheng Li (1)
  
  1. Department of Chemistry, Key Laboratory of Chemical Biology and Organic Chemistry of Henan Province, Key Laboratory of Applied Chemistry of Henan Universities, Zhengzhou University, Zhengzhou, 450052, China
  
• ISSN：1861-9541

文摘

Cyclopalladated ferrocenylimines as a novel kind of highly efficient palladium catalyst precursors, which are air-stable and easy to handle, have been successfully applied in a wide variety of catalytic reactions ranging from classical reactions, such as Heck, Suzuki, Sonogashira and Buchwald-Hartwig couplings, to cyanation, addition reactions of arylboronic acids, and coupling reactions involving terminal alkynes. The preliminary achievements regarding their applications to homogeneous catalysis are concisely described herein.