Selective extraction and determination of fluoroquinolones in bovine milk samples with montmorillonite magnetic molecularly imprinted polymers and capillary electrophoresis

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• 作者：Hongwu Wang ; Yanqing Liu ; Shoulian Wei ; Su Yao…
• 关键词：Fluoroquinolone ; Montmorillonite magnetic molecularly imprinted polymer ; Magnetic solid ; phase extraction ; Capillary electrophoresis ; Bovine milk
• 刊名：Analytical and Bioanalytical Chemistry
• 出版年：2016
• 出版时间：January 2016
• 年：2016
• 卷：408
• 期：2
• 页码：589-598
• 全文大小：1,131 KB
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• 作者单位：Hongwu Wang (1)
  Yanqing Liu (1)
  Shoulian Wei (1)
  Su Yao (1)
  Jiali Zhang (2)
  Huichang Huang (1)
  
  1. School of Chemistry & Chemical Engineering, Zhaoqing University, Zhaoqing, 526061, China
  2. Department of Chemistry, East China Jiaotong University, Nanchang, 330013, China
  
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Analytical Chemistry
  Food Science
  Inorganic Chemistry
  Physical Chemistry
  Monitoring, Environmental Analysis and Environmental Ecotoxicology
  
• 出版者：Springer Berlin / Heidelberg
• ISSN：1618-2650

文摘

A sensitive and selective method for separating fluoroquinolones (FQs) from bovine milk samples was successfully developed using montmorillonite magnetic molecularly imprinted polymers (MMMIPs) as adsorbents. MMMIPs were prepared using montmorillonite as carrier, fleroxacin (FLE) as template molecule, and Fe₃O₄ magnetite as magnetic component. MMMIPs possessed high adsorption capacity of 46.3 mg g−1 for FLE. A rapid and convenient magnetic solid-phase extraction procedure coupled with capillary electrophoresis was established with MMMIPs as adsorbents for simultaneous and selective extraction of four FQs in bovine milk samples. Limits of detection ranged between 12.9 and 18.8 μg L−1, and the RSDs were between 1.8 % and 8.6 %. The proposed method was successfully applied to spike bovine milk samples with recoveries of 92.7 %–108.6 %. Keywords Fluoroquinolone Montmorillonite magnetic molecularly imprinted polymer Magnetic solid-phase extraction Capillary electrophoresis Bovine milk