A fiber optic sensor for determination of 2,4-dichlorophenol based on iron(II) phthalocyanine catalysis

详细信息    查看全文

• 作者：Yonghong Wang ; Yilin Tong ; Jun Huang …
• 关键词：2 ; 4 ; dichlorophenol ; iron(II) phthalocyanine ; phase delay change ; fiber optic sensor ; stability
• 刊名：Journal of Wuhan University of Technology--Materials Science Edition
• 出版年：2015
• 出版时间：December 2015
• 年：2015
• 卷：30
• 期：6
• 页码：1317-1320
• 全文大小：998 KB
• 参考文献：[1]Jantra J, Zilouei H, Liu J, et al. Microbial Biosensor for the Analysis of 2, 4-Dichlorophenol[J]. Anal. Lett., 2005, 38: 1071-083CrossRef
  [2]Mckinley R, Plant JA, Bell JNB, et al. Endocrine Disrupting Pesticides: Implications for Risk Assessment[J]. Environment International, 2008, 34: 168-83CrossRef
  [3]Mehmood Z, Kelly DE, Kelley SL. Cytochrome P450 3A4 Mediated Metabolism of 2, 4-dichlorophenol[J]. Chemosphere, 1997, 34 (11): 2281-291CrossRef
  [4]Peng JF, Liu JF, Hu XL. Direct Determination of Chlorophenols in Environmental Water Samples by Hollow Fiber Supported Ionic Liquid Membrane Extraction Coupled with High-performance Liquid Chromatography[J]. J. Chromatogr. A, 2007, 1139: 165-70CrossRef
  [5]Donald F, Gurka SP, Richard T. Environmental Applications of Gas Chromatography/Atomic Emission Detection[J]. Anal. Chem., 1997, 69: 2411-417CrossRef
  [6]Natalia C, Nerea A, Pilar VIL, et al. Capillary Gas Chromatography with Atomic Emission Detection for Determining Chlorophenols in Water and Soil Samples[J]. Anal. Chim. Acta, 2005, 552: 182-89CrossRef
  [7]Rosanam MA, Regina S, Wilson FJ, et al. Selective Trace Level Analysis of Phenolic Compounds in Water by Flow Injection Analysis-Membrane Introduction Mass Spectrometry[J]. Environ. Sci. Technol., 2001, 35: 2084-088CrossRef
  [8]Mahugo CS, Padron MET, Ferrera ZS, et al. Development of a Solidphase Microextraction Method with Micellar Desorption for the Determination of Chlorophenols in Water Samples Comparison with Conventional Solid-phase Microextraction Method[J]. J. Chromatogr. A, 2007, 1140: 13-0CrossRef
  [9]Huang YP, Li J, Ma WH, et al. Efficient H2O2 Oxidation of Organic Pollutants Catalyzed by Supported Iron Sulfophenylporphyrin under Visible Light Irradiation[J]. J. Phys. Chem. B, 2004, 108: 7263-270CrossRef
  [10]Wang J, Chen G, Chatrathi MP, et al. Capillary Electrophoresis Microchip with a Carbon Nanotube-Modified Electrochemical Detector[J]. Anal. Chem., 2004, 76: 298-02CrossRef
  [11]Grace WM, Veronika QM, and Greg MS. Chlorinated Phenol Analysis Using off-Line Solid-Phase Extraction and Capillary Electrophoresis Coupled with Amperometric Detection and a Boron-Doped Diamond Microelectrode[J]. Anal. Chem., 2005, 77: 6542-548CrossRef
  [12]Dilsat O, Kagan K, Burcu M, et al. Heterostructured Fluorohectorite Clayasan Electrochemical Sensor for the Detection of 2, 4-Dichlorophenol and the Herbicide 2, 4-D[J]. Chem. Mater., 2002, 14: 1755-761CrossRef
  [13]Nicolette RH, Tesfaye TW, Omotayo A, et al. Microsomal Cytochrome P450-3A4 (CYP3A4) Nanobiosensor for the Determination of 2, 4-dichlorophenol-An Endocrine Disruptor Compound[J]. Electrochim. Acta, 2009, 54: 1925-931CrossRef
  [14]Doong RA, Tsai HC. Immobilization and Characterization of Sol-gelencapsulated Acetylcholinesterase Fiber-optic Biosensor[J]. Anal. Chim. Acta, 2001, 434: 239-46CrossRef
  [15]Tong YL, Li DP, Huang J, et al. Enhancing Heterogeneous Catalytic Activity of Iron (II) Phthalocyanine by Ethanol and Its Application in 2, 4-Dichlorophenol Detection[J]. J. Wuhan Univ. Tech., 2014, 29(3): 567-71CrossRef
  [16]Kasuga K, Tsutsui M. Some New Developments in the Chemistry of Metallophthalocyanines[J]. Coord. Chem. Rev., 1980, 32: 67-5CrossRef
  [17]Huang J, Fang H, Liu C, et al. A Novel Fiber Optic Biosensor for the Determination of Adrenaline Based on Immobilized Laccase Catalysis[J]. Anal. Lett., 2008, 41: 1430-442CrossRef
  
• 作者单位：Yonghong Wang (1)
  Yilin Tong (2) (3)
  Jun Huang (2)
  Kun Li (2)
  Huichao Liu (2)
  Liyun Ding (2)
  Mingtian Li (4)
  
  1. Wuhan University of Technology Hospital, Wuhan, 430070, China
  2. National Engineering Laboratory for Fiber Optic Sensing Technology, Wuhan University of Technology, Wuhan, 430070, China
  3. Mechanical and Electrical Engineering College, Hankou University, Wuhan, 430212, China
  4. College of Materials and Chemical Engineering, Sichuan University of Science and Engineering, Zigong, 643000, China
  
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Materials Science
  Chinese Library of Science
  
• 出版者：Wuhan University, co-published with Springer
• ISSN：1993-0437

文摘

A new fiber optic sensor based on the oxidation of 2,4-dichlorophenol (DCP) catalyzed by iron(II) phthalocyanine (Fe(II)Pc) was developed for the determination of DCP. The optical oxygen sensing film containing fluorescence indicator Ru(bpy)₃Cl₂ was used to detect the consumption of oxygen in solution. Moreover, a lock-in amplifier was used to determine the lifetime of the sensor head by detecting its phase delay change. The results reveal that the sensor has a linear detection range of 1.0×10-6 - 9.0×10-5 mol/L and a response time of 5 min. The sensor also has high selectivity, good repeatability and stability. It can be used effectively to determine DCP concentration in real samples. Key words 2,4-dichlorophenol iron(II) phthalocyanine phase delay change fiber optic sensor stability