High thermal conductive composites based on flake graphite filled in a partial compatible polyamide 6/polypropylene

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• 作者：Huagen Xu ; Haidi Zhou ; Xiaodong Chen ; Yinfeng Liu
• 刊名：Polymer Science Series A
• 出版年：2015
• 出版时间：September 2015
• 年：2015
• 卷：57
• 期：5
• 页码：644-655
• 全文大小：1,678 KB
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• 作者单位：Huagen Xu (1)
  Haidi Zhou (1)
  Xiaodong Chen (1)
  Yinfeng Liu (1)
  
  1. Department of Polymer Materials, Shanghai University, Shanghai, 200444, China
  
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Polymer Sciences
  Russian Library of Science
  
• 出版者：MAIK Nauka/Interperiodica distributed exclusively by Springer Science+Business Media LLC.
• ISSN：1555-6107

文摘

In this study, a series of thermally conductive materials was obtained based on flake graphite (FG) filled in a partially compatible system of polyamide 6 (PA6)/polypropylene (PP) blends at a loading of 30 wt % of FG. The thermal conductivity of PA6/PP/FG composites containing 1 wt % of the compatibilizer PP-graft-maleic anhydride (MAH) reached 2.703 W/(m K). The SEM images show that FG formed a long thermally conductive pathway in the partially compatible system. The result of Fourier transform infrared analysis indicates that the compatibilizer changes the compatibility between PA6 and PP and affects the distribution of FG. The crystallization behavior of the composites studied by X-ray diffraction and differential scanning calorimetry further proved that the filler in the composites distributed rationally. The impact strength and dynamic mechanical analysis confirmed that when the compatibilizer content was 1 wt %, the system was in a partially compatible state. The dynamic rheology of the composites was also studied to understand the effect of the distribution of FG on the conductivity of the composites. The article is published in the original.