Selective hydrogenation of ethyl benzoate over Ni–B amorphous alloys supported on γ-Al2O3

详细信息    查看全文

• 作者：Xin Wen ; Zhen Zhao ; Yingying Cao ; Huixian Dong…
• 关键词：Amorphous alloy ; Catalyst ; Hydrogenation ; Ethyl benzoate ; Stability
• 刊名：Research on Chemical Intermediates
• 出版年：2015
• 出版时间：September 2015
• 年：2015
• 卷：41
• 期：9
• 页码：6351-6361
• 全文大小：990 KB
• 参考文献：1.A. Roucoux, Top. Organomet. Chem. 16, 261 (2005)
  2.J. Schulz, A. Roucoux, H. Patin, Chem. Commun. 6, 535 (1999)View Article
  3.H. Liu, T. Jiang, B. Han, S. Liu, Y. Zhou, Science 326, 1250 (2009)View Article
  4.Y. Wang, J. Yao, H. Li, D. Su, M. Antonietti, J. Am. Chem. Soc. 133, 2362 (2011)View Article
  5.A. Gual, C. Godard, S. Castillón, C. Claver, Dalton Trans. 39, 11499 (2010)View Article
  6.V. Mévellec, A. Roucoux, E. Ramirez, K. Philippot, B. Chaudret, Adv. Synth. Catal. 346, 72 (2004)View Article
  7.M. Zahmak?ran, Y. Román-Leshkov, Y. Zhang, Langmuir 28, 60 (2012)View Article
  8.D.J.M. Snelders, N. Yan, W. Gan, G. Laurenczy, P.J. Dyson, ACS Catal. 2, 201 (2012)View Article
  9.K.A. Keane, J. Catal. 66, 347 (1991)
  10.H. Li, D. Zhang, G. Li, Y. Xu, Y. Lu, H. Li, Chem. Commun. 46, 791 (2010)View Article
  11.H. Li, H. Li, J. Zhang, W. Dai, M. Qiao, J. Catal. 246, 301 (2007)View Article
  12.W. Wang, Y. Yang, J. Bao, H. Luo, Catal. Commun. 11, 100 (2009)View Article
  13.J.H. Kwak, J. Hu, D. Mei, C.W. Yi, D.H. Kim, C.H.F. Peden, L.F. Allard, J. Szanyi, Science 325, 1670 (2009)View Article
  14.R.M. Ravenelle, J.R. Copeland, W.G. Kim, J.C. Crittenden, C. Sievers, ACS Catal. 1, 552 (2011)View Article
  15.A. Kirilin, P. Maki-Arvela, M. Rupp, E. Toukoniitty, N. Kumar, K. Kordas, L.M. Kustov, T. Salmi, D.Y. Murzin, Res. Chem. Intermed. 36, 193 (2010)View Article
  16.S. Wei, H. Cui, J. Wang, S. Zhuo, W. Yi, L. Wang, Z. Li, Particuology 9, 69 (2011)View Article
  17.G. Bai, L. Niu, Z. Zhao, N. Li, F. Li, M. Qiu, F. He, G. Chen, Z. Ma, J. Mol. Catal. A Chem. 363, 411 (2012)View Article
  18.G. Bai, X. Wen, Z. Zhao, F. Li, H. Dong, M. Qiu, Ind. Eng. Chem. Res. 52, 2266 (2013)View Article
  19.G. Bai, Z. Zhao, H. Dong, L. Niu, Y. Wang, Q. Chen, ChemCatChem 6, 655 (2014)View Article
  20.J.A. Anderson, A. Athawale, F.E. Imrie, F.M. McKenna, A. McCue, D. Molyneux, K. Power, M. Shand, R.P.K. Wells, J. Catal. 27, 9 (2010)View Article
  21.P.T.M. Do, A.J. Foster, J. Chen, R.F. Lobo, Green Chem. 14, 1388 (2012)View Article
  22.J.H. Kwak, R. Tonkyn, D. Tran, D. Mei, S.J. Cho, L. Kovarik, J.H. Lee, C.H.F. Peden, J. Szanyi, ACS Catal. 2, 1432 (2012)View Article
  23.F. Jin, H. Long, W. Song, G. Xiong, X. Guo, X. Wang, Energy Fuels 27, 3394 (2013)View Article
  24.W. Wang, Y. Yang, H. Luo, H. Peng, F. Wang, Ind. Eng. Chem. Res. 50, 10936 (2011)View Article
  25.Z. Zhu, J. Ma, L. Xu, L. Xu, H.X. Li, H. Li, ACS Catal. 2, 2119 (2012)View Article
  26.W. Wang, M. Qiao, J. Yang, S. Xie, J. Deng, Appl. Catal. A Gen. 163, 101 (1997)View Article
  27.L. Ma, W. Huang, J. Yang, J. Deng, J. Phys. IV 7, 909 (1997)
  
• 作者单位：Xin Wen (1) (2)
  Zhen Zhao (1)
  Yingying Cao (1)
  Huixian Dong (1)
  Chen Liu (1)
  Hailong Chu (1)
  Guoyi Bai (1)
  
  1. Key Laboratory of Chemical Biology of Hebei Province, College of Chemistry and Environmental Science, Hebei University, No. 180 Wusi East Road, Baoding City, 071002, Hebei, People’s Republic of China
  2. Hebei Chemical and Pharmaceutical College, Shijiazhuang, 050026, Hebei, People’s Republic of China
  
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Catalysis
  Physical Chemistry
  Inorganic Chemistry
  
• 出版者：Springer Netherlands
• ISSN：1568-5675

文摘

A series of Ni–B amorphous alloys supported on γ-Al2O3 was prepared by an impregnation chemical reduction method and tested in the selective hydrogenation of ethyl benzoate to ethyl cyclohexane carboxylate. The effect of different metal additives on the activity of the supported Ni–B amorphous alloys was investigated. It was found that the addition of small amounts of Pd to Ni–B amorphous alloy supported on γ-Al2O3 could markedly improve its activity and the yield of ethyl cyclohexane carboxylate can reach 88.1?% under the optimal reaction conditions. Furthermore, this catalyst could be recycled eight times without appreciable loss of its initial activity, much better than the unsupported one. The Ni–Pd–B amorphous alloy was proven to be highly dispersed on the surface and in the pores of γ-Al2O3, resulting in its larger BET area, more active Ni species, better stability, and hence accounting for its good catalytic performance.