Sorption and desorption of pymetrozine on six Chinese soils
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- 作者：Mingxing Gao ; Yingying Li ; Hong Yang…
- 关键词：pymetrozine ; sorption ; desorption ; soil
- 刊名：Frontiers of Environmental Science & Engineering
- 出版年：2016
- 出版时间：February 2016
- 年：2016
- 卷：10
- 期：1
- 页码：1-10
- 全文大小：442 KB
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Yingying Li (1)
Hong Yang (1)
Yucheng Gu (3)
1. Jiangsu Key Laboratory of Pesticide Science, College of Sciences, Nanjing Agricultural University, Nanjing, 210095, China
2. Syngenta Nantong Crop Protection Co., Ltd., Nantong Economic & Technological Development Area, Nantong, 226009, China
3. Syngenta Jealott鈥檚 Hill International Research Centre, Bracknell, Berkshire, RG42 6EY, UK - 刊物主题：Environment, general;
- 出版者：Springer Berlin Heidelberg
- ISSN：2095-221X
文摘
Pymetrozine is a selective insecticide with a unique chemical structure and mode to control hemipteran and homopteran. While pymetrozine has brought great benefits to crop production by killing insects, its residues in soil may have a detrimental effect on environment. Therefore, it is of great importance to investigate its behaviors in soil. In this study, the sorption and desorption of pymetrozine on six Chinese soils were investigated using a batch equilibrium approach to understand its mobile behavior in the soils. Both sorption and desorption isotherms of pymetrozine were in good agreement with the Freundlich model. The sorption coefficient K F varied between 3.37 and 58.32 mL路g鈭? and the sorption isotherms were nonlinear, with 1/n ranging from 0.57 to 0.91. A regression equation was proposed to predict the sorption of pymetrozine on six different soil samples: log K F = 4.3708 鈭?4.5709 脳 log (pH in 0.01mol路L鈭? CaCl2) + 0.4700 脳 log OC% + 0.0057 脳 sand (%) + 0.0022 脳 CEC(clay), with R 2 = 0.9982. The organic carbon content of soil positively affected the sorption of pymetrozine, but soil pH had a negative effect on the sorption. Additionally, effects of CaCl2 concentration, soil to solution ratio and pesticide form were investigated. The sorption was promoted with an increase in soil to solution ratio and a decrease in CaCl2 concentration. The possible variation of the five formulated products of pymetrozine was also investigated. Keywords pymetrozine sorption desorption soil