Production and Evaluation of Physicochemical Characteristics of Paddy Husk Bio-char for its C Sequestration Applications
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  • 作者:Salman Raza Naqvi ; Yoshimitsu Uemura ; Noridah Osman ; Suzana Yusup
  • 关键词:Paddy husk ; Bio ; char ; Yield ; Carbon stability ; C sequestration
  • 刊名:BioEnergy Research
  • 出版年:2015
  • 出版时间:December 2015
  • 年:2015
  • 卷:8
  • 期:4
  • 页码:1800-1809
  • 全文大小:1,414 KB
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  • 作者单位:Salman Raza Naqvi (1) (2)
    Yoshimitsu Uemura (1)
    Noridah Osman (1)
    Suzana Yusup (3)

    1. Center for Biofuel and Biochemical Research, Department of Chemical Engineering, Universiti Teknologi PETRONAS, Bandar Seri Iskandar, 31750, Tronoh, Perak, Malaysia
    2. School of Chemical and Material Engineering (SCME), National University of Science and Technology (NUST), H-12, Islamabad, Pakistan
    3. Biomass Processing Laboratory, Universiti Teknologi PETRONAS, Bandar Seri Iskandar, 31750, Tronoh, Perak, Malaysia
  • 刊物类别:Chemistry and Materials Science
  • 刊物主题:Chemistry
    Biomaterials
    Biochemical Engineering
    Bioorganic Chemistry
  • 出版者:Springer New York
  • ISSN:1939-1242
文摘
Bio-char is a carbon-rich solid material generated by thermochemical conversion process (pyrolysis) of lignocellulosic biomass, and its viability as a sustainable material has received increasing attention for environmental remediation. The relationship between bio-char properties and its applicability as a soil amendment is still not conclusive. The purpose of this research is to study the bio-char physical and chemical properties from an agricultural residue to examine the quality criteria for carbon sequestration and agricultural uses. Pyrolysis temperature was shown to have a strong impact on production and characteristics of bio-char samples. The bio-char yield decreased with increasing temperatures (350-50 °C). According to proximate and ultimate analysis data, temperature has the strongest impact on carbon stability of bio-char (stability increased at higher temperature). The volatile matter decreased while fixed carbon content increased with the increase of pyrolysis temperature. To evaluate further bio-char quality, the relationships between (O/C and H/C molar ratio) and (H/C and volatile matter) of raw paddy husk and produced bio-char at various temperatures is proposed. SEM, FT-IR, and 13C NMR findings are in well agreement with thermogravimetric and proximate analysis of the bio-char that structural and physicochemical properties were significantly influenced by pyrolysis temperature. CO2 adsorption rate increased with increasing temperature. Bio-char produced at 450 °C showed higher absorption capability and could be a potential sustainable substrate for C sequestration and soil amendment. Keywords Paddy husk Bio-char Yield Carbon stability C sequestration

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