Kinetic study of the catalytic pyrolysis of paddy husk by use of thermogravimetric data and the Coats–Redfern model

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• 作者：Salman Raza Naqvi ; Yoshimitsu Uemura ; Noridah Osman…
• 关键词：Biomass ; Catalytic pyrolysis ; Paddy husk ; ZSM ; 5 ; MCM ; 22 ; ITQ ; 2
• 刊名：Research on Chemical Intermediates
• 出版年：2015
• 出版时间：December 2015
• 年：2015
• 卷：41
• 期：12
• 页码：9743-9755
• 全文大小：1,511 KB
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• 作者单位：Salman Raza Naqvi (1)
  Yoshimitsu Uemura (1)
  Noridah Osman (1)
  Suzana Yusup (2)
  
  1. Department of Chemical Engineering, Center for Biofuel and Biochemical Research, Universiti Teknologi PETRONAS, Bandar Seri Iskandar, 31750, Tronoh, Perak, Malaysia
  2. Biomass Processing Laboratory, Universiti Teknologi PETRONAS, Bandar Seri Iskandar, 31750, Tronoh, Perak, Malaysia
  
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Catalysis
  Physical Chemistry
  Inorganic Chemistry
  
• 出版者：Springer Netherlands
• ISSN：1568-5675

文摘

Thermogravimetric data, the Coats–Redfern free integral method, and correlation coefficients obtained by use of different reaction models were used to study the kinetic characteristics of non-catalytic and catalytic pyrolysis of biomass. Zeolite catalysts (ZSM-5, MCM-22, and ITQ-2) were mixed with the biomass in the ratio 1:10. Analysis of thermogravimetric data revealed that thermal decomposition occurred at 240-50 °C for both non-catalytic and catalytic pyrolysis of biomass. Two temperature regions, region I 240-30 °C and region II 360-50 °C, were identified and a best-fit model describing the behavior of non-catalytic and catalytic biomass pyrolysis was obtained. Addition of catalyst reduces the activation energy in first region then increases it in the second region for all reaction orders. Chemical reaction and diffusion-controlled reaction mechanisms could be kinetically characterized and enabled good description of the nature of biomass pyrolysis. Keywords Biomass Catalytic pyrolysis Paddy husk ZSM-5 MCM-22 ITQ-2