Stabilization of hydrogen peroxide using tartaric acids in Fenton and Fenton-like oxidation

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• 作者：Hyung Suk Oh ; Jeong-Jin Kim ; Young-Hun Kim
• 关键词：Fenton Oxidation ; Fenton ; like Reactions ; Stabilization ; Hydrogen Peroxide ; Life ; time ; Tartaric Acid
• 刊名：Korean Journal of Chemical Engineering
• 出版年：2016
• 出版时间：March 2016
• 年：2016
• 卷：33
• 期：3
• 页码：885-892
• 全文大小：477 KB
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• 作者单位：Hyung Suk Oh (1)
  Jeong-Jin Kim (2)
  Young-Hun Kim (3)
  
  1. Department of Applied Chemistry, Andong National University, Andong, Gyeongbuk, 36729, Korea
  2. Department of Earth and Environmental Science, Andong National University, Andong, Gyeongbuk, 36729, Korea
  3. Department of Environmental Engineering, College of Engineering, Andong National University, Andong, Gyeongbuk, 36729, Korea
  
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Industrial Chemistry and Chemical Engineering
  Catalysis
  Materials Science
  Biotechnology
  
• 出版者：Springer New York
• ISSN：1975-7220

文摘

The stabilization of hydrogen peroxide is a key factor in the efficiency of a Fenton reaction. The stability of hydrogen peroxide was evaluated in a Fenton reaction and Fenton-like reactions in the presence of tartaric acid as a stabilizer. The interactions between ferrous or ferric iron and tartaric acid were observed through spectroscopic monitoring at variable pH around pKa1 and pKa2 of the stabilizer. Ferric iron had a strong interaction with the stabilizer, and the strong interaction was dominant above pKa2. At a low pH, below pKa1, the stabilizing effect was at its maximum and the prolonged life-time of hydrogen peroxide gave a higher efficiency to the oxidative degradation of nitrobenzene. In Fenton-like reactions with hematite, the acidic conditions caused dissolution of iron from an iron oxide, and an increase in iron species was the result. Tartaric acid showed a stabilizing effect on hydrogen peroxide in the Fentonlike system. The stabilization by tartaric acid might be due to an inhibition of catalytic activity of dissolved iron, and the stabilization strongly depends on the ionization state of the stabilizer.