Effect of modified silica on the crystallization and degradation of poly(3-hydroxybutyrate)

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• 作者：Shinn-Gwo Hong (1)
  Shih-Che Huang (1)
  
  1. Department of Chemical Engineering and Materials Science ; Yuan-Ze University ; Chung-Li ; 320 ; Taiwan
  
• 关键词：Polyhydroxybutyrate ; Silica ; Degradation ; Crystallization ; Methyl methacrylate ; Amidoamine
• 刊名：Journal of Thermal Analysis and Calorimetry
• 出版年：2015
• 出版时间：March 2015
• 年：2015
• 卷：119
• 期：3
• 页码：1693-1702
• 全文大小：500 KB
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• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Sciences
  Polymer Sciences
  Physical Chemistry
  Inorganic Chemistry
  Measurement Science and Instrumentation
  
• 出版者：Akad茅miai Kiad贸, co-published with Springer Science+Business Media B.V., Formerly Kluwer Academic
• ISSN：1572-8943

文摘

The crystallization and thermal degradation behaviors of poly(3-hydroxybutyrate) (PHB) filled with surface-modified silicas were analyzed by Fourier transform infrared spectroscopy (FTIR), differential scanning calorimetry (DSC), and dynamic thermogravimetric analysis (TG). The results of FTIR and TG confirmed that the substantial amounts of methyl methacrylate (MMA) and amidoamine (AMDA) were successfully grafted onto the hydrophilic silica surfaces. From DSC and TG analyses, it was indicated that the crystallization rate, crystallinity, melting temperature (T m), content of the high T m crystals, and thermal stability of PHB were affected by the type and amount of the silicas used and changed with the grafted chemicals. The hydrophobic silica has a better effect on enhancing crystallization rate and thermal stability of PHB than the hydrophilic silica due to the better compatibility with PHB. However, the MMA and AMDA grafted onto the hydrophilic silica surfaces effectively improved the crystallization and degradation effects of the hydrophilic silica. The addition of two parts AMDA-modified silica in a hundred parts PHB has the best improvement in terms of of the crystallization, melting characteristics, and thermal stability of PHB.