Aerobic oxidation of p-cresols to 4-hydroxy benzaldehydes catalyzed by cobaltous chloride/NHPI/salen-Cu(II) catalytic system

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• 作者：Wenchan Ma ; Yuecheng Zhang ; Xiujuan Li ; Jiquan Zhao
• 关键词：p ; cresol ; 2 ; bromo ; p ; cresol ; Aerobic oxidation ; Cobaltous chloride ; N ; hydroxyphthalimide ; Cu(II) ; salen complexes
• 刊名：Research on Chemical Intermediates
• 出版年：2015
• 出版时间：June 2015
• 年：2015
• 卷：41
• 期：6
• 页码：3855-3863
• 全文大小：500 KB
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• 作者单位：Wenchan Ma (1)
  Yuecheng Zhang (1)
  Xiujuan Li (1)
  Jiquan Zhao (1)
  
  1. School of Chemical Engineering and Technology, Hebei University of Technology, Tianjin, 300130, People鈥檚 Republic of China
  
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Catalysis
  Physical Chemistry
  Inorganic Chemistry
  
• 出版者：Springer Netherlands
• ISSN：1568-5675

文摘

Oxidation of 2-methoxy-p-cresol, p-cresol, 2-bromo-p-cresol to their corresponding 4-hydroxybenzaldehydes with atmospheric molecular oxygen as oxidant and a combination of cobaltous chloride and N-hydroxyphthalimide (NHPI) as catalyst in methanol has been investigated for the first time. The results indicated that the reaction progress was related to the substituents in the structures of the substrates: the electron-donating group methoxy favors the aerobic reaction but the electron-withdrawing group Br is detrimental to the reaction. The introduction of salen-Cu(II) complexes as the third component into the cobaltous chloride/NHPI catalytic system can considerably improve the aerobic oxidation of p-cresol and 2-brom-p-cresol to the corresponding 4-hydroxybenzaldes.