Effect of Plastic Deformation on the Crystal Structure and Crystallization Activation Energy of Ni-W-P Alloy Coating

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• 作者：Yuehua Wang ; Meiqi Yu ; Qi Qiao ; Fei You…
• 关键词：effective activation energy ; large plastic deformation ; Ni ; W ; P alloy ; phase transformation ; thermal analysis
• 刊名：Journal of Materials Engineering and Performance
• 出版年：2015
• 出版时间：July 2015
• 年：2015
• 卷：24
• 期：7
• 页码：2653-2657
• 全文大小：469 KB
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• 作者单位：Yuehua Wang (1)
  Meiqi Yu (1) (2)
  Qi Qiao (1)
  Fei You (1)
  Cailing Li (1)
  Zhefeng Xu (2)
  Kazuhiro Matsugi (2)
  Jinku Yu (1)
  
  1. State Key Laboratory of Metastable Materials Science and Technology, Yanshan University, Qinhuangdao, 066004, Hebei, People’s Republic of China
  2. Graduate School of Engineering, Hiroshima University, 1-4-1. Kagamiyama, Higashi-Hiroshima, 739-8527, Japan
  
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Characterization and Evaluation Materials
  Materials Science
  Tribology, Corrosion and Coatings
  Quality Control, Reliability, Safety and Risk
  Engineering Design
  
• 出版者：Springer New York
• ISSN：1544-1024

文摘

Jet electrodeposition method was used to prepare Ni-W-P amorphous alloy coating and effects of plastic deformation on the crystal structure and crystallization kinetics were investigated. Based on the results of differential scanning calorimeter, x-ray diffractometer and transmission electron microscope, it can be seen that when the plastic deformation is up to 20%, the Ni-W-P amorphous alloy coating begins to crystallize. An increase of plastic deformation will lead to a decrease of crystallization temperature as well as a decrease of crystallization activation energy calculated by Kissinger equation. The effective activation energy is reduced from 268.63?kJ/mol in the as-deposited state to 246.63?kJ/mol in the cold deformation up to 40%. Analyses were presented to discuss the possible mechanism for the effect of plastic deformation on the crystallization kinetics of the Ni-W-P amorphous alloy coatings.