Design and fabrication of semiconductor photocatalyst for photocatalytic reduction of CO2 to solar fuel

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• 作者：Xin Li ; Jiuqing Wen ; Jingxiang Low ; Yueping Fang ; Jiaguo Yu
• 刊名：Science China Materials
• 出版年：2014
• 出版时间：December 2014
• 年：2014
• 卷：57
• 期：1
• 页码：70-100
• 全文大小：6009KB
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• 作者单位：Xin Li (1) (2)
  Jiuqing Wen (2)
  Jingxiang Low (1)
  Yueping Fang (2)
  Jiaguo Yu (1) (3)
  
  1. State Key Laboratory of Advanced Technology for Material Synthesis and Processing, Wuhan University of Technology, Wuhan, 430070, China
  2. College of Science, South China Agricultural University, Guangzhou, 510642, China
  3. Department of Physics, Faculty of Science, King Abdulaziz University, Jeddah, 21589, Saudi Arabia
  
• 刊物类别：Materials Science, general; Chemistry/Food Science, general;
• 刊物主题：Materials Science, general; Chemistry/Food Science, general;
• 出版者：Science China Press
• ISSN：2199-4501

文摘

The shortage of fossil fuels and the disastrous pollution of the environment have led to an increasing interest in artificial photosynthesis. The photocatalytic conversion of CO₂ into solar fuel is believed to be one of the best methods to overcome both the energy crisis and environmental problems. It is of significant importance to efficiently manage the surface reactions and the photo-generated charge carriers to maximize the activity and selectivity of semiconductor photocatalysts for photoconversion of CO₂ and H₂O to solar fuel. To date, a variety of strategies have been developed to boost their photocatalytic activity and selectivity for CO₂ photoreduction. Based on the analysis of limited factors in improving the photocatalytic efficiency and selectivity, this review attempts to summarize these strategies and their corresponding design principles, including increased visible-light excitation, promoted charge transfer and separation, enhanced adsorption and activation of CO₂, accelerated CO₂ reduction kinetics and suppressed undesirable reaction. Furthermore, we not only provide a summary of the recent progress in the rational design and fabrication of highly active and selective photocatalysts for the photoreduction of CO₂, but also offer some fundamental insights into designing highly efficient photocatalysts for water splitting or pollutant degradation. , CO₂. CO₂ , CO₂ CO₂, CO₂CO₂ , CO₂