Disproportionation of cyclohexadienes and cyclohexene under the action of catalysts based on supported tetranuclear potassium carbonylruthenate K2[Ru4(CO)13]
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- 作者：S. M. Yunusov ; S. Rummel ; E. S. Kalyuzhnaya ; V. B. Shur
- 关键词：cyclohexadienes ; cyclohexene ; disproportionation ; ruthenium ; potassium carbonylmetallates ; clusters ; C ; H bond activation ; supported catalysts ; heterogeneous catalysis
- 刊名：Russian Chemical Bulletin
- 出版年：2014
- 出版时间：April 2014
- 年：2014
- 卷：63
- 期：4
- 页码：843-847
- 全文大小：172 KB
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17. S. Carrá, V. Ra - 作者单位：S. M. Yunusov (1)
S. Rummel (2)
E. S. Kalyuzhnaya (1)
V. B. Shur (1)
1. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian Federation
2. Institut für Oberfl?chenmodifizierung e.V., Permoserstrasse 15, D-04303, Leipzig, Germany - 刊物类别：Chemistry and Materials Science
- 刊物主题：Chemistry
Chemistry
Organic Chemistry
Inorganic Chemistry
Russian Library of Science - 出版者：Springer New York
- ISSN：1573-9171
文摘
The deposition of tetranuclear potassium carbonylruthenate K2[Ru4(CO)13] onto carbon Sibunit, SiO2, γ-Al2O3, and MgO followed by the thermal decomposition of the supported anionic cluster at 300 °C in an H2 or Ar flow leads to systems capable of catalyzing the disproportionation of cyclohexa-1,3-diene and cyclohexa-1,4-diene. The reactions proceed at room temperature to form mixtures of benzene and cyclohexene, benzene, cyclohexene, and cyclohexane, or benzene and cyclohexane. The catalytic systems developed are also active in cyclohexene disproportionation to benzene and cyclohexane at 100-30 °C.