Nanostructuring gold wires as highly durable nanocatalysts for selective reduction of nitro compounds and azides with organosilanes
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- 作者：Huifang Guo ; Xiuling Yan ; Yun Zhi ; Zhiwen Li ; Cai Wu ; Chunliang Zhao…
- 关键词：nanocatalyst ; gold ; catalysis ; reduction
- 刊名：Nano Research
- 出版年：2015
- 出版时间：April 2015
- 年：2015
- 卷：8
- 期：4
- 页码：1365-1372
- 全文大小：2,231 KB
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Xiuling Yan (3)
Yun Zhi (1)
Zhiwen Li (3)
Cai Wu (1)
Chunliang Zhao (1)
Jing Wang (1)
Zhixin Yu (4)
Yi Ding (2) (3)
Wei He (1)
Yadong Li (5)
1. School of Medicine and Tsinghua-Peking Joint Center for Life Sciences, Tsinghua University, Beijing, 100084, China
3. School of Chemistry and Chemical Engineering, Shandong University, Jinan, 250100, China
4. Department of Petroleum Engineering, University of Stavanger, Stavanger, 4036, Norway
2. Institute for New Energy Materials and Low-Carbon Technologies, and School of Materials Science and Engineering, Tianjin University of Technology, Tianjin, 300384, China
5. Department of Chemistry, Tsinghua University, Beijing, 100084, China - 刊物类别：Chemistry and Materials Science
- 刊物主题：Chinese Library of Science
Chemistry
Nanotechnology - 出版者：Tsinghua University Press, co-published with Springer-Verlag GmbH
- ISSN：1998-0000
文摘
A general method is developed to prepare durable hybrid nanocatalysts by nanostructuring the surface of gold wires via simple alloying and dealloying. The resulting nanoporous gold/Au (NPG/Au) wire catalysts possess nanoporous skins with their thicknesses on robust metal wires specified in a highly controllable manner. As a demonstration, the as-obtained NPG/Au was shown to be a highly active, chemo-selective, and recyclable catalyst for the reduction of nitro compounds and azides using organosilanes as reducing agents.