Design, synthesis, and optical/electronic properties of a series of sphere-rod shape amphiphiles based on the C60-oligofluorene conjugates
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- 作者：Fu-ai Teng ; Feng-li Liu ; Lu Han ; Zheng-ju Zhu…
- 关键词：Shape amphiphiles ; Fullerene ; Oligofluorene ; Donor ; acceptor dyads
- 刊名：Chinese Journal of Polymer Science
- 出版年：2017
- 出版时间：April 2017
- 年：2017
- 卷：35
- 期：4
- 页码：503-514
- 全文大小：
- 刊物类别：Chemistry and Materials Science
- 刊物主题：Polymer Sciences; Industrial Chemistry/Chemical Engineering; Characterization and Evaluation of Materials; Condensed Matter Physics;
- 出版者：Chinese Chemical Society and Institute of Chemistry, CAS
- ISSN：1439-6203
- 卷排序：35
文摘
A series of sphere-rod shape amphiphiles were designed and synthesized by connecting the rod-like oligofluorenes with different lengths (OFn) to the different positions of the spherical [60]fullerene (C60) through a rigid linkage. The conjugates were characterized by 1H-NMR, 13C-NMR, FTIR, EA and MALDI-TOF mass spectrometry. The optical and electronic properties of the conjugates were studied by UV-Vis absorption spectroscopy, fluorescence spectrometry, and cyclic voltammetry. The results from UV-Vis absorption spectroscopy and cyclic voltammetry indicated that the energy profiles of C60 and OFn remained unchanged when different lengths of OFn were attached to C60. The electron affinities of the OFn-C60 conjugates were close to that of C60, while slight electronic interaction was found between the two individual chromophores (C60 and OFn) in their ground states. The fluorescence spectra exhibited a complete fluorescence quenching in the toluene solution, suggesting an effective energy transfer from OFn to C60. It presents a systematic study on the self-assembly, structure-property relationship, and potential technical applications of the conjugates.