Direct Electrodeposition of Hollowed Ag Nanostructures on ITO Glass for Reproducible SERS Application

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• 作者：Xudong Cheng ; Juncao Bian ; Zhengfeng Huang ; Zhaoguo Zhang ; Peimei Dong…
• 关键词：Hollowed Ag nanostructure ; Twin defect ; Electrodeposition ; SERS ; Reproducibility
• 刊名：Plasmonics
• 出版年：2016
• 出版时间：October 2016
• 年：2016
• 卷：11
• 期：5
• 页码：1279-1283
• 全文大小：784 KB
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Biotechnology
  Nanotechnology
  Biophysics and Biomedical Physics
  Biochemistry
  
• 出版者：Springer US
• ISSN：1557-1963
• 卷排序：11

文摘

Hollowed Ag nanostructures are, for the first time, electrodeposited on ITO glass without use of surfactant. The hollowed Ag nanostructure was investigated via a collaboration of scanning electron microscopy (SEM), XRD, X-ray photoelectron spectroscopy (XPS), high-resolution transmission electron microscopy (HRTEM), XRD, and UV-vis. Results exhibited that the formation of the hollowed Ag nanostructure can be interpreted as the synergy effect of twin defect and low nucleation driving force. Surface-enhanced Raman scattering (SERS) spectra of rhodamine 6G and adenine molecules adsorbed on the surface of these Ag nanostructures were recorded. The smallest RSD of 1651 cm−1 Raman bands of rhodamine 6G was 14.7 %, indicating that the hollowed Ag nanostructures can be utilized for reproducible SERS application. Through comparison, it was found the good crystallinity was beneficial for SERS.