Research on fast solid-state chemical reactions at the Siberian Synchrotron and Terahertz Radiation Center

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• 作者：B. P. Tolochko ; K. V. Zolotarev
• 关键词：synchrotron radiation ; X ; ray diffraction ; solid state chemistry ; ultrafast reaction ; detonation ; electrochemistry ; hydrogenization ; nanodiamonds ; in situ investigation ; catalyst structure
• 刊名：Journal of Structural Chemistry
• 出版年：2016
• 出版时间：December 2016
• 年：2016
• 卷：57
• 期：7
• 页码：1288-1313
• 全文大小：
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Inorganic Chemistry; Physical Chemistry; Atomic, Molecular, Optical and Plasma Physics; Atomic/Molecular Structure and Spectra; Solid State Physics;
• 出版者：Pleiades Publishing
• ISSN：1573-8779
• 卷排序：57

文摘

The potent equipment of the shared-use center “Siberian Synchrotron and Terahertz Radiation Center” at Budker Institute of Nuclear Physics of the Siberian Branch of the Russian Academy of Sciences (BINP SB RAS) enables conduction of time-resolved X-ray diffraction experiments using synchrotron radiation of the VEPP-3/VEPP-4 storage rings. These experiments are performed mostly for institutions of the Siberian Branch of the Russian Academy of Sciences (SB RAS). The experiments yielded novel techniques, which have been implemented for investigation into the dynamics of the nucleation and formation of nanoparticles under explosion and shock wave impact with a nanosecond-scale time resolution (the X-ray exposure time is 73 ps), dynamics of structural transformations in chemical reactions, and kinetics of chemical reactions during gasless combustion (SHS) with a millisecond-scale time resolution, obtaining structural information about the state of catalysts and so on.