参考文献:1. Meunier B. Chemistry: Catalytic degradation of chlorinated phenols. Science, 2002, 296: 270-71 CrossRef 2. Vione D, Maurino V, Minero C, et al. New processes in the environmental chemistry of nitrite. 2. The role of hydrogen peroxide. Environ Sci Technol, 2003, 37: 4635-641 CrossRef 3. Theruvathu J A, Aravindakumar C T, Flyunt, R, et al. Fenton chemistry of 1,3-dimethyluracil. J Am Chem Soc, 2001, 123: 9007-014 CrossRef 4. Buxton G V, Greenstock C L, Helman W P, et al. Critical review of rate constants for reactions of hydrated electrons, hydrogen atoms and hydroxyl radicals in aqueous solution, J Phys Chem Ref Data, 1988, 17: 513-86 5. Bach R D, Dmitrenko O. The “somersault-mechanism for the P-450 hydroxylation of hydrocarbons. the intervention of transient inverted metastable hydroperoxides. J Am Chem Soc, 2006, 128: 1474-488 CrossRef 6. Perez-Estrada L A, Malato S, Gernjak W, et al. Photo-fenton degradation of diclofenac: identification of main intermediates and degradation pathway. Environ Sci Technol, 2005, 39: 8300-306 CrossRef 7. Bohne C, Faulhaber K, Giese B, et al. Studies on the mechanism of the photo-induced DNA damage in the presence of acridizinium salts-involvement of singlet oxygen and an unusual source for hydroxyl radicals. J Am Chem Soc, 2005, 127: 76-5 CrossRef 8. Sallustio B C, DeGraaf Y C, Weekley J S, et al. Bioactivation of carboxylic acid compounds by UDP-glucuronosyltransferases to DNA-damaging intermediates: Role of glycoxidation and oxidative stress in genotoxicity. Chem Res Toxicol, 2006, 19: 683-91 CrossRef 9. Southworth B A, Voelker B M. Hydroxyl radical production via the photo-fenton reaction in the presence of fulvic acid. Environ Sci Technol, 2003, 37: 1130-136 CrossRef 10. Fang H J, Ouyang B, Qin Y, et al. Study on the reaction of carbon disulfide with hydroxyl radical in aqueous solution, Chin Sci Bull, 2005, 50: 2832-835 11. Foley S, Rotureau P, Pin S, et al. Radiolysis of confined water: Production and reactivity of hydroxyl radicals. Angew Chem Int Ed, 2005, 44: 110-12 CrossRef 12. Poole J S, Shi X, Hadad C M, et al. Reaction of hydroxyl radical with aromatic hydrocarbons in nonaqueous solutions: A laser flash photolysis study in acetonitrile. J Phys Chem A, 2005, 109: 2547-551 CrossRef 13. Sorokin A, SJris J L, Meunier B. Efficient oxidative dechlorination and aromatic ring cleavage of chlorinated phenols catalyzed by iron sulfophthalocyanine. Science, 1995, 268: 1163-166 CrossRef 14. Wu Z C, Zhou M H. Partial degradation of phenol by advanced electrochemical oxidation process. Environ Sci Technol, 2001, 35: 2698-703 CrossRef 15. Wu Z C, Cong Y Q, Zhou M H, et al. p-Nitrophenol abatement by the combination of electrocatalysis and activated carbon. Chem Eng J, 2005, 106: 83-0 CrossRef 16. Wu Z C, Cong Y Q, Zhou M H, et al. Removal of phenolic compounds by electro-assisted advanced process for wastewater purification. Korean J Chem Eng, 2002, 19: 866-70 17. Blatchley III E R, Margetas D, Duggirala R. Copper catalysis in chloroform formation duringwater chlorination. Water Res, 2003, 37: 4385-394 CrossRef 18. Environmental Protection Agency. Disinfectants, disinfection byproducts, final rule-National Primary Drinking Water Regulations. Federal Register, 1998, 63: 69390-9476
作者单位:YanQing Cong (1) ZuCheng Wu (1) YuQiong Li (1)
1. Department of Environmental Engineering, Zhejiang University, Hangzhou, 310027, China
ISSN:1861-9541
文摘
The most reactive hydroxyl radical (-/sup>OH) was generated by electrochemical approach with safe water as the complete atom source. The direct evidence for -/sup>OH formation was obtained by electron spin resonance method. The powerful -/sup>OH electrochemically generated could effectively degrade organic pollutants and reduce the toxicity of wastewater. Electrochemical disinfection by "OH was considerably efficient even without the aid of active chlorine. Bacteria inactivation of 99.99% was achieved for contact time of 30 min and current density of 5 mA·cm?. In comparison with active chlorine, -/sup>OH is rather attractive as a promising environmentally benign disinfectant and opens a new route for microbial inactivation.