The unified method for computing thermodynamic properties of natural zeolites based on their crystallochemical formulas

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• 作者：O. V. Eremin ; E. S. Epova ; O. S. Rusal’…
• 刊名：Russian Journal of Inorganic Chemistry
• 出版年：2016
• 出版时间：August 2016
• 年：2016
• 卷：61
• 期：8
• 页码：1003-1012
• 全文大小：336 KB
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Inorganic Chemistry
  Russian Library of Science
  
• 出版者：MAIK Nauka/Interperiodica distributed exclusively by Springer Science+Business Media LLC.
• ISSN：1531-8613
• 卷排序：61

文摘

The standard thermodynamic potentials of natural zeolites in universal stoichiometric representation are computed. The enthalpies are estimated using linear deconvolution into chemical elements for calibration minerals. The entropies are computed using the additive scheme for oxide components; the Gibbs free energies are computed based on the calculated standard thermodynamic functions and entropies of thermochemically simple compounds.Original Russian Text © O.V. Eremin, E.S. Epova, O.S. Rusal’, R.A. Filenko, V.A. Bychinskii, K.V. Chudnenko, S.V. Fomichev, V.A. Krenev, 2016, published in Zhurnal Neorganicheskoi Khimii, 2016, Vol. 61, No. 8, pp. 1053–1062.