Two new piperazine templated lanthanide sulfates with 2D corrugated layered crystal structures

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• 作者：Deng Zhang (1)
  Xin-rong Fan (1)
  Yun Lu (1)
  Yan Xu (1)
  
• 关键词：Solvothermal synthesis ; Lanthanide sulfate ; Layered structure ; Luminescence
• 刊名：Chemical Research in Chinese Universities
• 出版年：2013
• 出版时间：February 2013
• 年：2013
• 卷：29
• 期：1
• 页码：10-14
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• 作者单位：Deng Zhang (1)
  Xin-rong Fan (1)
  Yun Lu (1)
  Yan Xu (1)
  
  1. State Key Laboratory of Materials-oriented Chemical Engineering, College of Chemistry and Chemical Engineering, Nanjing University of Technology, Nanjing, 210009, P. R. China
  
• ISSN：2210-3171

文摘

Two new piperazine templated lanthanide sulfates (C4N2H12)1.5[Ln(SO4)3(H2O)]·H2O[Ln=Gd(1), Tb(2)] have been synthesized solvothermally and structurally characterized by single crystal X-ray diffraction(XRD), infrared(IR) spectroscopy, thermal analysis, fluorescent spectra and inductively coupled plasma(ICP). Single crystal X-ray diffraction reveals that both compounds 1 and 2 crystallized in the monoclinic crystal system, with space group P21/c and cell dimensions: a=0.64468(19) nm, b=2.9979(9) nm, c=0.9818(3) nm, β=101.271(4)°, V=1.8608(10) nm3, Z=4 for compound 1; a=0.64259(19) nm, b=3.0010(9) nm, c=0.9812(3) nm, β=101.229(4)°, V=1.8560(10) nm3, Z=4 for compound 2. Compounds 1 and 2 are isomorphous and have similar 2D corrugated inorganic frameworks fabricated via the connection of single chains and S2O4 groups, while fully protonated piperazine cations and water molecules are located between the inorganic layers. The solid state luminescent properties of compound 2 were investigated and it displayed a typical luminescent property of Tb3+ with excitation wavelength at 371 nm.