Synthesis and characterization of TMU-16-NH2 metal-organic framework nanostructure upon silk fiber: Study of structure effect on morphine and methyl orange adsorption affinity

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• 作者：Amir Reza Abbasi ; Jalal ad-Din Aali ; Azadeh Azadbakht ; Ali Morsali…
• 关键词：Metal ; organic framework ; Silk ; Nanoparticle ; Methyl orange ; Morphine
• 刊名：Fibers and Polymers
• 出版年：2015
• 出版时间：May 2015
• 年：2015
• 卷：16
• 期：5
• 页码：1193-1200
• 全文大小：2,483 KB
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• 作者单位：Amir Reza Abbasi (3)
  Jalal ad-Din Aali (3)
  Azadeh Azadbakht (1)
  Ali Morsali (2)
  Vahid Safarifard (2)
  
  3. Faculty of Chemistry, Razi University, Kermanshah, 67194, Islamic Republic of Iran
  1. Department of Chemistry, Faculty of Science, Islamic Azad University, Khorramabad, Islamic Republic of Iran
  2. Department of Chemistry, Faculty of Sciences, Tarbiat Modares University, Tehran, 14155-4838, Islamic Republic of Iran
  
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Polymer Sciences
  
• 出版者：The Korean Fiber Society
• ISSN：1875-0052

文摘

Thin films of a three-dimensional porous Zn(II)-based metal-organic framework, [Zn₂(H₂N-BDC)₂(4-bpdh)]· 3DMF (TMU-16-NH₂), containing azine-functionalized pores, were deposited on surfaces of silk fiber via a stepwise manner. The effect of sequential dipping steps in growth of TMU-16-NH₂ upon fiber has been studied. These systems depicted a decrease in the size accompanying a decrease in the sequential dipping steps. The deposition of TMU-16-NH₂ upon silk fiber was monitored by XRPD and FT-IR spectroscopy. The TMU-16-NH₂ upon silk fiber can serve as a host for encapsulating morphine (Mph) and methyl orange (MO).