Ultrasonic cavitation assisted hydrogen implosion synthesis of Pt nanoparticles/nitrogen-doped graphene nanohybrid scrolls and their electrocatalytic oxidation of methanol

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• 作者：Yunsong Zhang (1) (2)
  Xiaohua Zhang (1)
  Jinhua Chen (1)
  
  1. State Key Laboratory of Chemo/Biosensing and Chemometrics ; College of Chemistry and Chemical Engineering ; Hunan University ; 410082 ; Changsha ; People鈥檚 Republic of China
  2. College of Basic Science ; Sichuan Agricultural University ; 625014 ; Yaan ; People鈥檚 Republic of China
  
• 关键词：Graphene nanoscrolls ; Electrocatalyst ; Nanohybrids ; Electrooxidation ; Methanol
• 刊名：Ionics
• 出版年：2015
• 出版时间：May 2015
• 年：2015
• 卷：21
• 期：5
• 页码：1287-1294
• 全文大小：984 KB
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• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Electrochemistry
  Materials Science
  Physical Chemistry
  Condensed Matter
  Renewable Energy Sources
  Electrical Power Generation and Transmission
  
• 出版者：Springer Berlin / Heidelberg
• ISSN：1862-0760

文摘

Based on the ultrasonic cavitation assisted hydrogen implosion method, Pt nanoparticles (NPs)/nitrogen-doped graphene nanohybrid scrolls (Pt NPs/N-GNSs) were synthesized. As the results of the N-doping and high reduction degree of graphene, and scroll structure of the nanohybrids, the Pt NPs/N-GNSs electrocatalyst shows excellent performance in the direct oxidation of methanol: low onset and peak potentials, high oxidation current, and good long-term cycle stability. The Pt NPs/N-GNSs should have great promising applications in heterogeneous catalysis and fuel cells.