Effect of the degree of substitution on the hydrophobicity of acetylated cellulose for production of liquid marbles

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• 作者：Xingman Zhou ; Xinxing Lin ; Kevin L. White ; Shan Lin ; Hui Wu ; Shilin Cao…
• 关键词：Cellulose acetate ; Degree of substitution ; Hydrophobicity ; Liquid marble
• 刊名：Cellulose
• 出版年：2016
• 出版时间：February 2016
• 年：2016
• 卷：23
• 期：1
• 页码：811-821
• 全文大小：1,164 KB
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• 作者单位：Xingman Zhou (1) (2)
  Xinxing Lin (1)
  Kevin L. White (3)
  Shan Lin (1)
  Hui Wu (1)
  Shilin Cao (1)
  Liulian Huang (1)
  Lihui Chen (1) (2)
  
  1. College of Material Engineering, Fujian Agriculture and Forestry University, No. 15, Shangxiadian Road, Fuzhou, 350002, People’s Republic of China
  2. College of Food Science, Fujian Agriculture and Forestry University, Fuzhou, 350002, Fujian, People’s Republic of China
  3. Akron Ascent Innovations, Akron, OH, 44311, USA
  
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Bioorganic Chemistry
  Physical Chemistry
  Organic Chemistry
  Polymer Sciences
  
• 出版者：Springer Netherlands
• ISSN：1572-882X

文摘

Acetylated cellulose powders with varying degree of substitution (DS) were prepared by reacting cellulose with acetic anhydride. The effect of DS on the hydrophobic properties of acetylated cellulose was examined based on contact angle and mechanical stability measurements. The surface energy of the acetylated cellulose decreases with increasing DS, and for DS of 0.39, the acetylated cellulose was able to encapsulate a water droplet to form a liquid marble. The corresponding cellulose acetate powder-over-water spreading coefficient was ca. 8.9. Increasing DS also improved the mechanical stability of the liquid marble. This study opens important perspectives for the precise control of DS of cellulose acetate for various practical applications in membranes, filters, scaffolds, and textiles. Keywords Cellulose acetate Degree of substitution Hydrophobicity Liquid marble