Trace and major elements in geological samples from Itingusssú River Basin, Sepetiba Bay––Rio de Janeiro

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• 作者：D. R. Araripe (1) drararipe@vm.uff.br
  A. V. B. Bellido (2)
  S. R. Patchineelam (3)
  R. M. Latini (2)
  L. F. Bellido (4)
  D. I. T. Fávaro (5)
• 关键词：Sediments – Trace elements – Rare earth elements
• 刊名：Journal of Radioanalytical and Nuclear Chemistry
• 出版年：2011
• 出版时间：November 2011
• 年：2011
• 卷：290
• 期：2
• 页码：381-389
• 全文大小：1.8 MB
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• 作者单位：1. Departamento de Química Analítica, Universidade Federal Fluminense, Niterói, RJ, Brazil2. Departamento de Físico-Química, Universidade Federal Fluminense, Niterói, RJ, Brazil3. Departamento de Geoquímica, Universidade Federal Fluminense, Niterói, RJ, Brazil4. Instituto de Engenharia Nuclear, Rio de Janeiro, RJ, Brazil5. Instituto de Pesquisas Energéticas, S?o Paulo, SP, Brazil
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Nuclear Chemistry
  Physical Chemistry
  Nuclear Physics, Heavy Ions and Hadrons
  Diagnostic Radiology
  Inorganic Chemistry
  
• 出版者：Akad茅miai Kiad贸, co-published with Springer Science+Business Media B.V., Formerly Kluwer Academic
• ISSN：1588-2780

文摘

The Itingussú drainage basin is situated at 22°44′–22°55′ SL and 44°53′–43°55′ WL, in Coroa-Grande district, Sepetiba Bay, southwest of Rio de Janeiro, Brazil. Its total area is less than 10 km2 and includes a waterfall with three drop offs. The study area is located in a granitic pre-Cambrian embasement, discharging in a mangrove forest fringe. This work attempts to investigate the influence of lithology types in the elemental composition of soil of region and sediments of related mangrove. Instrumental neutron activation analysis and subsequent gamma-ray spectrometry were used. This technique enabled the measurement of at least twenty-one chemical elements. The more representative soil samples were enriched with U and Th. Multivariate Statistical Analysis showed that the soil and sediments formed in this area have been influenced by the leucocratic rocks, enriched with LREE and Th. The factorial analysis enables the identification of five factors of influence in the ordination of elements: presence of iron minerals (biotite); presence of allanite; marine influence in the sediment; differentiated kinetic of transport and diagenesis.