Arenetricarbonylchromium Complexes in Polymerization Transformations by Radical Initiation of Vinyl Polymerization

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• 作者：Lyudmila Semenycheva ; Alexander Artemov…
• 刊名：Journal of Inorganic and Organometallic Polymers and Materials
• 出版年：2016
• 出版时间：September 2016
• 年：2016
• 卷：26
• 期：5
• 页码：921-931
• 全文大小：869 KB
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Inorganic Chemistry
  Organic Chemistry
  Polymer Sciences
  
• 出版者：Springer New York
• ISSN：1574-1451
• 卷排序：26

文摘

The article is devoted to the systematization of investigations of arenetricarbonylchromium complexes in radical polymerization transformation at the initiation of vinyl polymerization. The presented data are shown that these compounds are promising and interesting model systems for the study of the phenomenon of the metal atom action on the reactivity of the monomer π-bond. The correlation between the structure of metal-containing monomers and polymerization parameters, as well as the molecular mass properties of the resulting polymers, are discussed.KeywordsArenetricarbonylchromium complexes(Co)polymerizationRadical initiationStable radicalA weak inhibitionReversible inhibition